THE ELECTROCHEMICAL OXIDATION OF ROUGH PLANT RAW MATERIALS
Abstract
Research result of process of electrochemical oxidation of rough plant raw materials: the mathematical planning of experiments, the researches, the creation of mathematical models. Authors defined optimum conditions of processing: temperature of the electrolyte is 70 degrees, the pH of electrolyte - treatment of rye straw and birch sawdust at pH equal 8,0–10,0 (25% of electricity), then at pH equal 4,0–6,0 (75% of electricity ), aspen sawdust at pH = 4,0–6,0, the anode density of current is 0,125 kA/m2, the initial concentration of sodium chloride is 30,0 kg/m3 of electrolyte, quantity of electricity is 0,9 kA·h/kg of raw materials.
After the electrochemical treatment of rye straw, birch and aspen sawdust, are identified reducing substances (6,0–6,3 wt.% of the raw materials), glucose (4,5–5,0 wt.% of the raw materials), oxygen-containing compounds of chlorine (ClO- of less than 0,001 kg/m3 electrolyte, ClO3- is 0,014–0,019 kg/m3 electrolyte), the mass of the residual solid (60–80 wt.% of raw material), ruthenium and titanium (the absence).
The method is planned for using in a forage production on purpose of eliminate the imbalance of sugars in a fodder diet of agricultural animals.Downloads
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Авруцкая И.А., Мухина И.Б., Архипова Т.А. Поведение органических компонентов грубого растительного сырья при электролизе хлоридных растворов // Электрохимия. 1996. Т. 32, №1. С.75–78.
Рузинов Л.П. Планирование эксперимента в химии и химической технологии. М., 1980. 280 с.
Выродова Л.П., Морозова С.Ф., Дегтярёва Н.Н. Инструкция по химико-технологическому контролю гидро-лизного производства, этилового спирта, кормовых дрожжей и технического фурфурола // Сборник трудов ВНИИ Гидролиз. Л., 1987. С. 45–52.
Зяблицева Е.В., Ряттель А.В., Зяблицева М.П., Лобастова Е.В. Электрохимическое окисление соломы // Совре-менные твердофазные технологии: теория, практика и инновационный менеджмент. Тамбов, 2010. С. 249–251.
Патент 2352140 (РФ). Способ обработки грубых кормов / М.П. Зяблицева, Л.Н. Толмачёва, Н.Б. Багаева, Е.В. Зяблицева, Е.В. Лобастова. 2009.
Патент 2352184 (РФ). Установка обработки грубых кормов / М.П. Зяблицева, Е. В. Зяблицева. 2009.
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