THE GAS CHROMATOGRAPHIC STUDY OF THERPENE AND FATTY ACID COMPOSITION OF MENTHA SPI-CATA GROWING IN THE MIDDLE URALS

UDC 615.32:547.9:543.54

  • Marina Gennadʹyevna Pervova I.Ya. Postovsky Institute of Organic Synthesis Ural Branch of RAS Email: pervova@ios.uran.ru
  • Ainakhanum Samitdinovna Misrikhanova I.Ya. Postovsky Institute of Organic Synthesis Ural Branch of RAS Email: misrihanova25@gmail.com
  • Mariya Andreyevna Samorukova I.Ya. Postovsky Institute of Organic Synthesis Ural Branch of RAS Email: eremina-masha@yandex.ru
  • Viktor Ivanovich Saloutin I.Ya. Postovsky Institute of Organic Synthesis Ural Branch of RAS Email: saloutin@ios.uran.ru
Keywords: Mentha spicata, terpenes, carvone, fatty acids, extraction, derivatization, gas chromatography

Abstract

The terpene and fatty acid composition in ethanol extracts of spearmint (lat. Mentha spicata) growing in the Middle Urals was studied by gas chromatography and gas chromatography-mass spectrometry. The qualitative and quantitative composition of the terpene fraction was studied depending on the part of the plant (leaves, stems, roots) and the storage method of the plant (freezing, drying). 30 components were found in the extracts, 24 were identified. It was found that the greatest amount of terpenes is contained in the extracts of spearmint leaves, the least in the root extracts, and the best way to preserve terpenes in the plant is drying. Limonene, 1,8-cineole, dihydrocarvone, β-bourbonene, β-caryophyllene, β-copaen, hydroxymethylfurfural were identified as the main components of the terpene fraction; (-)-carvone is found in the greatest amount. Changes in the composition and content of fatty acids in spearmint were investigated depending on the month of harvest (May-September). It was found that the main fatty acids found in spearmint are palmitoleic (16:1), palmitic (16:0), linoleic (18:2), linolenic (18:3), stearic (18:0), arachidic (20:0), behenic (22:0) acids with a predominant content of linolenic acid. It is shown that in the period May-September the relative content of unsaturated acids increases and exceeds the content of saturated acids by 4.2–4.7 times.

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Author Biographies

Marina Gennadʹyevna Pervova, I.Ya. Postovsky Institute of Organic Synthesis Ural Branch of RAS

кандидат химических наук, старший научный сотрудник лаборатории фторорганических соединений

Ainakhanum Samitdinovna Misrikhanova, I.Ya. Postovsky Institute of Organic Synthesis Ural Branch of RAS

лаборант-исследователь лаборатории фторорганических соединений

Mariya Andreyevna Samorukova, I.Ya. Postovsky Institute of Organic Synthesis Ural Branch of RAS

инженер-исследователь лаборатории фторорганических соединений

Viktor Ivanovich Saloutin, I.Ya. Postovsky Institute of Organic Synthesis Ural Branch of RAS

доктор химических наук, член-корреспондент РАН, заведующий лабораторией фторорганических соединений

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Published
2022-06-10
How to Cite
1. Pervova M. G., Misrikhanova A. S., Samorukova M. A., Saloutin V. I. THE GAS CHROMATOGRAPHIC STUDY OF THERPENE AND FATTY ACID COMPOSITION OF MENTHA SPI-CATA GROWING IN THE MIDDLE URALS // chemistry of plant raw material, 2022. № 2. P. 173-181. URL: http://journal.asu.ru/cw/article/view/10600.
Section
Low-molecular weight compounds