GRINDING OF FIBROUS SEMI-FINISHED PRODUCTS AS A MECHANOCHEMICAL PROCESS. MATHEMATICAL MODELING

UDC 676.024.61

  • Vladimir Robertovich Pen Reshetnev Siberian State University of Science and Technology Email: 2507@inbox.ru
  • Yuriy Davydovich Alachkevich Reshetnev Siberian State University of Science and Technology
  • Robert Zus'yevich Pen Reshetnev Siberian State University of Science and Technology Email: robertpen@yandex.ru
  • Svetlana Ivanovna Levchenko Reshetnev Siberian State University of Science and Technology Email: levchenko167@inbo.ru
  • Tat'yana Vladimirovna Pen Reshetnev Siberian State University of Science and Technology
Keywords: grinding, mechanochemistry, grinding dynamics, chemical kinetics

Abstract

It is known that the process of grinding fibrous semi-finished products proceeds in the form of four successive stages, accompanied by complex processes of fibrillation and hydration of fibers subjected to mechanical action. The development of these processes over time determines the dynamics of changes in cellulose fiber, which ultimately leads to the formation of the necessary paper-forming properties. The paper shows that the representation of the grinding of fibrous semi-finished products as a mechanochemical process makes it possible to formulate a mathematical model of the grinding dynamics based on the principles of formal kinetics. The latter makes it possible to single out the stages of the milling process in the form of a standard kinetic mechanism of successively occurring reactions. The corresponding model is presented as a system of ordinary differential equations with constant coefficients, the solution of which presents no fundamental difficulties. Since it is not the degree of destruction that is determined experimentally, but the degree of grinding, it is proposed to present the relationship between these values as a power series with a limitation in the form of a linear approximation. However, due to the large dimension, the parametric identification of the model has fundamental difficulties. The paper proposes a reduction method that allows overcoming the problem. The corresponding parameters are identified by comparing the model and the array of experimental data. The presented approach makes it possible to obtain an adequate closed mathematical description of the dynamics of grinding fibrous semi-finished products.

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Author Biographies

Vladimir Robertovich Pen, Reshetnev Siberian State University of Science and Technology

доктор химических наук, доцент, профессор кафедры автоматизации производственных процессов

Yuriy Davydovich Alachkevich, Reshetnev Siberian State University of Science and Technology

доктор технических наук, профессор, академик РАО, профессор кафедры машин и аппаратов промышленных технологий

Robert Zus'yevich Pen, Reshetnev Siberian State University of Science and Technology

доктор технических наук, профессор, профессор кафедры машин и аппаратов промышленных технологий

Svetlana Ivanovna Levchenko, Reshetnev Siberian State University of Science and Technology

кандидат химических наук, доцент, доцент кафедры химической технологии твердых ракетных топлив, нефтепродуктов и полимерных композиций

Tat'yana Vladimirovna Pen, Reshetnev Siberian State University of Science and Technology

аспирант

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Published
2023-12-15
How to Cite
1. Pen V. R., Alachkevich Y. D., Pen R. Z., Levchenko S. I., Pen T. V. GRINDING OF FIBROUS SEMI-FINISHED PRODUCTS AS A MECHANOCHEMICAL PROCESS. MATHEMATICAL MODELING // chemistry of plant raw material, 2023. № 4. P. 423-428. URL: http://journal.asu.ru/cw/article/view/11366.
Section
Technology