PEROXIDE CELLULOSE FROM WHEAT AND HEMP STEMS

UDC 676.166

  • Robert Zus'evich Pen Reshetnev Siberian State University of Science and Technology Email: robertpen@yandex.ru
  • Ida L'vovna Shapiro Reshetnev Siberian State University of Science and Technology
  • Natalja Viktorovna Karetnikova Reshetnev Siberian State University of Science and Technology Email: karetnikova.tata@yandex.ru
  • Roman Aleksandrovich Marchenko Reshetnev Siberian State University of Science and Technology Email: marchenkora@sibsau.ru
DOI_disc_logo https://doi.org/10.14258/jcprm.20230412954
Keywords: cellulose, wheat straw, cannabis, shive, hemp, delignification, iodine number, hydrogen peroxide, peracetic acid

Abstract

The wheat steams (Triticum sh.), hemp and shive from the technical cannabis (Cannabis sativa), wood of Siberia fir (Abies sibirica) was processed with the sodium hydrate (concentration NaOH 1 g-mol/dm3, liquid module 6, temperature 93 °C, length 2 hours), washed with water and delignificated by the “hydrogen peroxide – sulfuric acid – water” solution (initial concentration of the acetic acid 6 g-mol/dm3, hydrogen peroxide – also 6 g-mol/dm3 , sulfuric acid – 1.5% (mass.), liquid module 6, temperature of the isothermal process 93 °C, length 210 minutes). Simultaneously the same vegetable raw material was delignificated without alkaline preprocessing and without sulfuric acid catalyst at the cooking. The purpose of the study – estimation of the influence named factors on output and characteristic of the cellulose. Mathematical processing is performed with the methods of the cluster and dispersing analysis. Alkaline preprocessing has brought to reduction of the output and degree polymerization and to increase the iodine number only to celluloses from wheat straw. The additive catalytic amount of the sulfuric acid to cooking solution brought to the reduction of the output and degree polymerization and to increase the iodine number of the cellulose from all type used one-year vegetable raw. Under approaching choice technological cooking conditions it is possible reception of the product with the characteristics microcrystalline celluloses (the degree polymerization not above 300, iodine number not less 10 mg/g) with one-stage peroxide cooking without alkaline preprocessing and catalyst.

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Author Biographies

Robert Zus'evich Pen, Reshetnev Siberian State University of Science and Technology

доктор технических наук, профессор, профессор кафедры машин и аппаратов промышленных технологий, ведущий научный сотрудник лаборатории глубокой переработки растительного сырья

Ida L'vovna Shapiro, Reshetnev Siberian State University of Science and Technology

кандидат технических наук, старший научный сотрудник лаборатории глубокой переработки растительного сырья

Natalja Viktorovna Karetnikova, Reshetnev Siberian State University of Science and Technology

кандидат химических наук, доцент, доцент кафедры машин и аппаратов промышленных технологий

Roman Aleksandrovich Marchenko , Reshetnev Siberian State University of Science and Technology

кандидат технических наук, заведующий кафедрой машин и аппаратов промышленных технологий

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Published
2023-12-15
How to Cite
1. Pen R. Z., Shapiro I. L., Karetnikova N. V., Marchenko R. A. PEROXIDE CELLULOSE FROM WHEAT AND HEMP STEMS // chemistry of plant raw material, 2023. № 4. P. 415-422. URL: http://journal.asu.ru/cw/article/view/12954.
Issue
No 4 (2023)
Section
Technology

Copyright (c) 2023 chemistry of plant raw material

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