STRUCTURE OF POLYPHENOLS OF LEAVES TANNING SUMAC RHUS CORIARIA L.

UDC 547.982/83/84

  • Zhamollitdin Fazlitdinovich Ziyavitdinov Institute of Bioorganic Chemistry Academician A.S. Sadykov AS RUz Email: Jamolitdin@mail.ru
  • Yuliya Igorevna Oshchepkova Institute of Bioorganic Chemistry Academician A.S. Sadykov AS RUz Email: joshepkova05@rambler.ru
  • Nodira Gulyamzhanovna Abdulladzhanova Institute of Bioorganic Chemistry Academician A.S. Sadykov AS RUz Email: anodira73@rambler.ru
  • Shavkat Ismailovich Salikhov Institute of Bioorganic Chemistry Academician A.S. Sadykov AS RUz Email: joshepkova05@rambler.ru
DOI_disc_logo https://doi.org/10.14258/jcprm.2020016316
Keywords: Rhus coriaria L., Anacardiaceae family, chromatography, mass spectrum, structure, fragmentation, polyphenols

Abstract

The aim of this work is to study the composition and structural characteristics of the polyphenols of the tanning sumac Rhus coriaria L. of the Anacardiaceae family, growing in Uzbekistan, using a high-performance liquid chromatograph with a diode-matrix detector (HPLC-DAD) and a tandem temple mass-spectrometer (HPLC– Q-TOF-MS / MS).

The phenolic compounds of the aerial part (leaves) of Rhus coriaria L. plants of the Anacardiaceae family were studied. For the first time, polyphenol fractions were isolated from tanning sumac leaves using stepwise hydrophobic chromatography. By HPLC, as a result of semi-preparative chromatography from the fraction eluted with 30% ethanol, 9 individual compounds were obtained, in the amount of: R-1 – 0.5 mg, R-2 – 0.8 mg, R-3 – 2.3 mg, R-4 – 12.6 mg, R-5 – 34.5 mg, R-6 – 15 mg, R-7 – 8 mg, R-8 – 7.1 mg, R-9 – 45.5 mg As a result of mass spectrometric analyzes and NMR spectroscopy for individual polyphenols, it was established that the polyphenols isolated in the individual state consist of gallic acid and glucose, interconnected by an ester bond: mono-, di-, tri-, tetra-, penta- , hexa-, hepta-, octa- and non-O-galloyl-β-D-glucose.

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Author Biographies

Zhamollitdin Fazlitdinovich Ziyavitdinov, Institute of Bioorganic Chemistry Academician A.S. Sadykov AS RUz

кандидат химических наук, заместитель директора по науке и инновациям

Yuliya Igorevna Oshchepkova, Institute of Bioorganic Chemistry Academician A.S. Sadykov AS RUz

доктор химических наук, заведующая лабораторией химии белков и пептидов

Nodira Gulyamzhanovna Abdulladzhanova, Institute of Bioorganic Chemistry Academician A.S. Sadykov AS RUz

доктор химических наук, ведущий научный сотрудник лаборатории ЭТЛ

Shavkat Ismailovich Salikhov, Institute of Bioorganic Chemistry Academician A.S. Sadykov AS RUz

академик, директор

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Published
2020-03-05
How to Cite
1. Ziyavitdinov Z. F., Oshchepkova Y. I., Abdulladzhanova N. G., Salikhov S. I. STRUCTURE OF POLYPHENOLS OF LEAVES TANNING SUMAC RHUS CORIARIA L. // chemistry of plant raw material, 2020. № 1. P. 133-140. URL: http://journal.asu.ru/cw/article/view/6316.
Issue
No 1 (2020)
Section
Low-molecular weight compounds

Copyright (c) 2020 Khimiia rastitel'nogo syr'ia (Chemistry of plant raw material)

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