INVESTIGATION AND OPTIMIZATION OF COMPLEXATION OF MANGANESE (II) IONS WITH DIHY-DROQUERCETIN IN AQUEOUS SOLUTIONS

UDC 543.641:546.712:547.575:543.427.4:543.573

  • Yelena Vladimirovna Stolpovskaya Irkutsk Institute of Chemistry A.E. Favorsky SB RAS Email: stel@irioch.irk.ru
  • Natalya Nikolaevna Trofimova Irkutsk Institute of Chemistry A.E. Favorsky SB RAS Email: natrof@irioch.irk.ru
  • Vasily Anatolyevich Babkin Irkutsk Institute of Chemistry A.E. Favorsky SB RAS Email: babkin@irioch.irk.ru
  • Spartak Spiridonovich Khutsishvili Irkutsk Institute of Chemistry A.E. Favorsky SB RAS Email: khutsishvili_sp@yahoo.com
  • Roman Georgievich Zhitov Irkutsk State University Email: zhitovroman@gmail.com
  • Yelena Vladimirovna Chuparina Institute of Geochemistry named after A.P. Vinogradov SB RAS Email: lchup@igc.irk.ru
  • Artem Sergeevich Maltsev Institute of the Earth's Crust SB RAS Email: artemmaltsev1@gmail.com
DOI_disc_logo https://doi.org/10.14258/jcprm.2020037369
Keywords: dihydroquercetin, flavonoids, complex compounds, manganese ions, optimization, yield of the product

Abstract

The purpose of this work was to study and optimize the complexation reaction of Mn2+ ions with flavonoid dihydroquercetin (DHQ) in aqueous solutions. It was found that the interaction of DHQ (0.015–0.030 M) with manganese (II) salts at molar ratios of DHQ : Mn2+ from 1 : 1 to 1 : 3 at pH 6.9–7.9 leads to the formation of a complex compound (CC) with a stoichiometric ratio of metal : flavonoid ligand (Met : L) 1 : 1.

The conditions for the complexation of Mn2+ ions with dihydroquercetin at laboratory conditions optimized for the yield of the product, are proposed. The maximum yield of the complex (95%) was achieved at the interaction of DHQ with Mn(CH3COO)2∙4H2O under conditions: pH 7.7, 70 °C, the reaction time was 15 min, the molar ratio of the initial reagents DHQ: Mn2+ was 1 : 1.5, the initial concentrations were 0.020 M DHQ and 0.030 M Mn2+.

The most probable composition of the complex with the determination of the amount of bound water [MnL(OH)(H2O)2] and the structure of the complex were established using the data of thermogravimetry (TG), differential scanning calorimetry (DSC), elemental analysis and X-ray fluorescence analysis (XRF), confirmed by the data of total reflection X-ray fluorescence analysis (TXRF), and EPR spectroscopy data.

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Author Biographies

Yelena Vladimirovna Stolpovskaya, Irkutsk Institute of Chemistry A.E. Favorsky SB RAS

кандидат химических наук, старший научный сотрудник лаборатории химии древесины

Natalya Nikolaevna Trofimova, Irkutsk Institute of Chemistry A.E. Favorsky SB RAS

кандидат химических наук, начальник отдела аспирантуры

Vasily Anatolyevich Babkin, Irkutsk Institute of Chemistry A.E. Favorsky SB RAS

доктор химических наук, профессор, заведующий лабораторией

Spartak Spiridonovich Khutsishvili, Irkutsk Institute of Chemistry A.E. Favorsky SB RAS

старший научный сотрудник

Roman Georgievich Zhitov, Irkutsk State University

кандидат химических наук, научный сотрудник

Yelena Vladimirovna Chuparina, Institute of Geochemistry named after A.P. Vinogradov SB RAS

кандидат химических наук, старший научный сотрудник

Artem Sergeevich Maltsev, Institute of the Earth's Crust SB RAS

ведущий инженер

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Published
2020-10-22
How to Cite
1. Stolpovskaya Y. V., Trofimova N. N., Babkin V. A., Khutsishvili S. S., Zhitov R. G., Chuparina Y. V., Maltsev A. S. INVESTIGATION AND OPTIMIZATION OF COMPLEXATION OF MANGANESE (II) IONS WITH DIHY-DROQUERCETIN IN AQUEOUS SOLUTIONS // chemistry of plant raw material, 2020. № 3. P. 47-56. URL: http://journal.asu.ru/cw/article/view/7369.
Issue
No 3 (2020)
Section
Low-molecular weight compounds

Copyright (c) 2020 chemistry of plant raw material

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