FUNCTIONAL MATERIALS FROM WASTE PAPER. IV. COMPARATIVE STUDY OF FUNCTIONAL COMPOSITION, SUPRAMOLECULAR STRUCTURE AND MORPHOLOGY OF POWDER CELLULOSES ISOLATED FROM WASTE PAPER, PLANT CELLULOSES AND UNCONVENTIONAL RAW MATERIALS

UDC 676.038.22/677.014.84

  • Aleksandra Mikhaylovna Mikhailidi St. Petersburg State University of Industrial Technologies and Design Email: amikhailidi@yahoo.com
  • Vadim Ivanovich Markin Altai State University https://orcid.org/0000-0002-4853-9350 Email: markin@chemwood.asu.ru
  • Nina Efimovna Kotelnikova Institute of Macromolecular Compounds Russian Academy of Sciences https://orcid.org/0000-0002-0246-3661 Email: nkotel@mail.ru
DOI_disc_logo https://doi.org/10.14258/jcprm.20220110598
Keywords: waste paper, powder cellulose, FTIR transform spectroscopy, 13C NMR spectroscopy, wide-angle X-ray scattering, scanning electron microscopy

Abstract

A comparative study of the supramolecular structure, physico-chemical properties and morphology of powder celluloses (PCs) obtained from the waste paper of newsprint and cardboard, plant cellulose and unconventional raw materials was conducted using the methods of FTIR spectroscopy, high-resolution 13C NMR spectroscopy in the solid phase, wide-angle X-ray scattering and scanning electron microscopy (SEM). According to the results of FTIR and 13C NMR spectroscopy, the functional composition of PCs is similar to that of wood PCs and matches highly purified cellulose samples. The crystallographic structure of powder samples corresponds to the structure of cellulose I. The crystallinity and transverse dimensions of crystallites are 39.4% and 40.2% and 45 Å [110] and 54 Å [110] for PC from newsprint paper and cardboard, respectively. These values considerably exceed the analogous values for the initial waste paper samples. A comparative analysis of the SEM results showed a significant similarity of PCs fibers of different origin. The results of the study of the physico-chemical properties of PCs isolated from waste paper make it possible to predict their competitive application in comparison with plant PCs.

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Author Biographies

Aleksandra Mikhaylovna Mikhailidi, St. Petersburg State University of Industrial Technologies and Design

кандидат химических наук, доцент кафедры технологии полиграфического производства, доцент кафедры теоретической и прикладной химии

Vadim Ivanovich Markin, Altai State University

доцент кафедры органической химии, кандидат химических наук

Nina Efimovna Kotelnikova, Institute of Macromolecular Compounds Russian Academy of Sciences

доктор химических наук, ведущий научный сотрудник

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Published
2022-03-10
How to Cite
1. Mikhailidi A. M., Markin V. I., Kotelnikova N. E. FUNCTIONAL MATERIALS FROM WASTE PAPER. IV. COMPARATIVE STUDY OF FUNCTIONAL COMPOSITION, SUPRAMOLECULAR STRUCTURE AND MORPHOLOGY OF POWDER CELLULOSES ISOLATED FROM WASTE PAPER, PLANT CELLULOSES AND UNCONVENTIONAL RAW MATERIALS // chemistry of plant raw material, 2022. № 1. P. 93-104. URL: http://journal.asu.ru/cw/article/view/10598.
Issue
No 1 (2022)
Section
Biopolymers of plants

Copyright (c) 2022 chemistry of plant raw material

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