RESEARCH OF PHYSICAL AND CHEMICAL PROPERTIES OF WOOD PULSE ACTIVATED BY HYDRODYNAMIC METHOD

UDC 620.193.16, 620.93, 556.114

Keywords: sawdust, cavitation, mechanical activation, chemical composition, porous structure, functional groups, ligno-carbohydrate complex, hydrodynamic activation, cellulose, lignin, carbohydrate complex

Abstract

The work studied the effect of mechanical activation, hydrodynamically, on the physico-chemical properties of soft waste from mechanical processing of wood (sawdust). As a result of research, it has been established that during cavitation treatment, the chemical structure of sawdust is transformed, which ensures the production of hydrodynamically activated wood particles with a high content of reactive surface functional groups, which is caused by a change in the ligno-carbohydrate complex. It has been established that as a result of hydrodynamic activation, the amount of difficult-to-hydrolyze polysaccharides is reduced by 37%, while the proportions of easily hydrolyzable substances and substances of phenolic nature increase, respectively, by 12 and 25%. The transformation of the ligno-carbohydrate complex of wood particles during cavitation largely determines the change in the characteristics of their porous structure. An increase in the number of micropores by 1.5 times and large transport pores by 3 times during the cavitation process was established. The results obtained largely prove that the physical and chemical properties of hydrodynamically activated wood particles largely determine the possibility of obtaining non-toxic wood materials with high physical and mechanical properties without piezo-thermal effects.

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Author Biographies

Natal'ya Yur'yevna Demidenko, Siberian State University of Science and Technology named after Academician M.F. Reshetnev

кандидат технических наук, доцент кафедры химической технологии древесины и биотехнологии

Mikhail Andreyevich Bayandin, Siberian State University of Science and Technology named after Academician M.F. Reshetnev

кандидат технических наук, доцент кафедры химической технологии древесины и биотехнологии

Aleksey Valer'yevich Namyatov, Siberian State University of Science and Technology named after Academician M.F. Reshetnev

кандидат технических наук, ассистент кафедры химической технологии древесины и биотехнологии

Vladimir Nikolayevich Yermolin, Siberian State University of Science and Technology named after Academician M.F. Reshetnev

доктор технических наук, профессор кафедры химической технологии древесины и биотехнологии

References

Katrakov I.B., Markin V.I., Bazarnova N.G. Izvestiya AltGU, 2014, vol. 1, no. 3, pp. 204–208. DOI: 10.14258/izvasu(2014)3.1-37. (in Russ.).

Shiryayev D.V. Teploizolyatsionnyye materialy na osnove modifitsirovannykh metodom vzryvnogo avtogidroliza ot-khodov rastitel'nogo proiskhozhdeniya: avtoref. diss. … dokt. tekhn. nauk. [Thermal insulation materials based on waste of plant origin modified by explosive autohydrolysis: abstract of dissertation. ... doc. tech. Sci.]. Barnaul, 2013, 20 p. (in Russ.).

Yermolin V.N., Bayandin M.A., Kazitsin S.N., Namyatov A.V. Izvestiya VUZov. Lesnoy zhurnal, 2019, no. 5 (371), pp. 148–156. DOI: 10.17238/issn0536-1036.2019.5.148. (in Russ.).

Kazitsin S.N. Polucheniye drevesnykh plit bez svyazuyushchikh veshchestv iz mekhanoaktivirovannykh drevesnykh chas-tits: avtoref. diss. … kand. tekhn. nauk. [Preparation of wood boards without binders from mechanically activated wood particles: abstract of dissertation. ... cand. tech. Sci.]. Krasnoyarsk, 2018, 16 p. (in Russ.).

Bazarnova N.G., Katrakov I.B., Markin V.I. Rossiyskiy khimicheskiy zhurnal (Zhurnal Rossiyskogo khimicheskogo obshchestva im. D.I. Mendeleyeva), 2004, vol. 48, no. 3, pp. 108–115. (in Russ.).

Mokhirev A.P., Zyryanov M.A., Bulayev Ye.V. Universum: Tekhnicheskiye nauki, 2019, no. 11(68), pp. 67–69. (in Russ.).

Hon D.N.-S. Chemical Modification of Lignocellulosic Materials. Marcel Dekker, 1996, 370 p.

Hill C.A.S. Wood Modification: Chemical, Thermal and Other Processes. John Wiley & Sons Ltd, 2006, 248 p.

Hu F., Ragauskas A. Bioengineering Resources, 2012, vol. 5, pp. 1043–1066. DOI: 10.1007/s12155-012-9208-0.

Mikushina I.V. i dr. Khimiya v interesakh ustoychivogo razvitiya, 2002, vol. 10, no. 4, pp. 443–447. (in Russ.).

Lebedev I.V., Kazakov YA.V., Chukhchin D.G., Romanenko K.A. Khimiya rastitel'nogo syr'ya, 2018, no. 2, pp. 207–216. DOI: 10.14258/jcprm.2018022248. (in Russ.).

Marchenko R.A., Alashkevich Yu.D., Reshetova N.S. Khimiya rastitel'nogo syr'ya, 2012, no. 1, pp. 191–198. (in Russ.).

Komarov V.I. Deformatsiya i razrusheniye voloknistykh tsellyulozno-bumazhnykh materialov. [Deformation and de-struction of fibrous pulp and paper materials]. Arkhangel'sk, 2002, 440 p. (in Russ.).

Rogovin Z.A. Khimiya tsellyulozy. [Chemistry of cellulose]. Moscow, 1972, 519 p. (in Russ.).

Struktura i fiziko-khimicheskiye svoystva tsellyuloz i nanokompozitov na ikh osnove [Structure and physicochemical properties of celluloses and nanocomposites based on them], ed. L.A. Aleshina, V.A. Gurtov, N.V. Melekh. Petroza-vodsk, 2014, 240 p. (in Russ.).

Alashkevich Yu.D. Gidrodinamicheskiye yavleniya pri beznozhevoy obrabotke voloknistykh materialov. [Hydrody-namic phenomena during knifeless processing of fibrous materials]. Krasnoyarsk, 2004, 80 p. (in Russ.).

Petrunina Ye.A., Loskutov S.R., Bayandin M.A. i dr. Stroyeniye, svoystva i kachestvo drevesiny – 2018: materialy VI Mezhdunarod-nogo simpoziuma imeni B.N. Ugoleva, posvyashchennogo 50-letiyu Regional'nogo Koordinatsionnogo soveta po sovremennym problemam drevesinovedeniya. [Structure, properties and quality of wood - 2018: materials of the VI International Symposium named after B.N. Ugolev, dedicated to the 50th anniversary of the Regional Coordina-tion Council on Contemporary Problems of Wood Science]. Krasnoyarsk, 2018, pp. 158–161. (in Russ.).

Bykov A.V., Miroshnikov S.A., Mezhuyeva L.V. Vestnik OGU, 2009, no. 12 (106), pp. 77–80. (in Russ.).

Petrunina Ye.A., Loskutov S.R., Mironov P.V. Stroyeniye, svoystva i kachestvo drevesiny – 2018: materialy VI Mezhdunarodnogo simpoziuma imeni B.N. Ugoleva, posvyashchennogo 50-letiyu Regional'-nogo Koordinatsionnogo soveta po sovremennym problemam drevesinovedeniya. [Structure, properties and quality of wood - 2018: materials of the VI International Symposium named after B.N. Ugolev, dedicated to the 50th anniversary of the Regional Coordina-tion Council on modern problems of wood science]. Krasnoyarsk, 2018, pp. 161–165. (in Russ.).

GOST 4453-74. Ugol' aktivnyy osvetlyayushchiy drevesnyy poroshkoobraznyy. Tekhnicheskiye usloviya. [GOST 4453-74. Active charcoal brightening wood powder. Technical conditions]. Moscow, 1993, 23 p. (in Russ.).

GOST 6217-74. Ugol' aktivnyy drevesnyy droblenyy. Tekhnicheskiye usloviya (s Izmeneniyami N 1, 2, 3, 4). [GOST 6217-74. Crushed active charcoal. Technical specifications (with Amendments No. 1, 2, 3, 4)]. Moscow, 2003, 8 p. (in Russ.).

Dubinin M.M. Zhurnal fizicheskoy khimii, 1987, no. 5, pp. 1301–1305. (in Russ.).

Kel'tsev N.V. Osnovy adsorbtsionnoy tekhniki. [Fundamentals of adsorption technology]. Moscow, 1976, 512 p. (in Russ.).

Ryazanova T.V., Chuprova N.A., Isayeva Ye.V. Khimiya drevesiny. Ch. 2: Osnovnyye komponenty drevesiny: uchebnoye posobiye dlya studentov vuzov. [Chemistry of wood. Part 2: Basic components of wood: a textbook for uni-versity students]. Krasnoyarsk, 2011, 229 p. (in Russ.).

Pinjari D.V., Pandit A.B. Ultrasonics sonochemistry, 2010, vol. 17, pp. 845–852.

Khill K., Bember D. Ul'trazvuk v meditsine. Fizicheskiye osnovy primeneniya: monografiya. [Ultrasound in medicine. Physical basis of application: monograph]. Moscow, 2008, 542 p. (in Russ.).

Tsalagkas D. et al. Ultrasonics sonochemistry, 2021, vol. 72, 105462.

IUPAC Manual of Symbols and Terminology. Pure and Applied Chemistry, 1972, vol. 31, 578 p.

Kuznetsov B.N., Golovin Yu.G., Golovina V.V., Yeremina A.O., Levdanskiy V.A. Khimiya rastitel'nogo syr'ya, 2002, no. 2, pp. 57–61. (in Russ.).

Grunin Yu.B., Grunin L.Yu., Nikol'skaya Ye.A., Talantsev V.I. Vysokomolekulyarnyye soyedineniya. Ser. A, 2012, vol. 54, no. 3, pp. 397–405. (in Russ.).

Published
2023-10-02
How to Cite
1. Demidenko N. Y., Bayandin M. A., Namyatov A. V., Yermolin V. N. RESEARCH OF PHYSICAL AND CHEMICAL PROPERTIES OF WOOD PULSE ACTIVATED BY HYDRODYNAMIC METHOD // chemistry of plant raw material, 2023. № 3. P. 337-344. URL: http://journal.asu.ru/cw/article/view/11513.
Section
Technology