HYDROGENATION OF PINE WOOD IN SUPERCRITICAL ETHANOL WITH IR AND Pd-Ir CATALYSTS

UDC 54-16, 67.08

  • Aleksandr Sergeevich Kazachenko Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center "Krasnoyarsk Scientific Center SB RAS", Siberian Federal University Email: leo_lion_leo@mail.ru
  • Roman Vladimirovich Borisov Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center "Krasnoyarsk Scientific Center SB RAS", Siberian Federal University Email: roma_boris@list.ru
  • Angelina Viktorovna Miroshnikova Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center "Krasnoyarsk Scientific Center SB RAS", Siberian Federal University Email: miroshnikova35@gmail.com
  • Sergey Viktorovich Baryshnikov Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center "Krasnoyarsk Scientific Center SB RAS" Email: leo_lion_leo@mail.ru
  • Olga Sergeevna Selezneva Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center "Krasnoyarsk Scientific Center SB RAS" Email: olihgff@gmail.com
  • Andrey Mikhailovich Skripnikov Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center "Krasnoyarsk Scientific Center SB RAS", Siberian Federal University Email: and-skripnikov@yandex.ru
DOI_disc_logo https://doi.org/10.14258/jcprm.20240415086
Keywords: hydrogenation, pine, Palladium, iridium, carbon nanotubes, reductive catalytic fractionation

Abstract

Iridium and palladium-iridium catalysts on carbon nanotubes were obtained by the hydrothermal method. The effect of the resulting catalysts on the yield and composition of pine wood hydrogenation products obtained in supercritical ethanol was studied. The influence of iridium and iridium-palladium catalysts in the process of hydrogenation of pine wood has been established. The use of iridium-palladium catalysts in the process of hydrogenation of pine wood leads to an increase in its conversion by 8 wt.%, the yield of liquid products by 11 wt.%, while reducing the yield of solid products by 8 wt.% and gaseous products by 3 wt.%. In the presence of catalysts during the hydrogenation of pine wood, the yield of monomeric methoxyphenols increases to 22.0 wt.%.

Downloads

Metrics

PDF views
73
Dec 04 '24Dec 07 '24Dec 10 '24Dec 13 '24Dec 16 '24Dec 19 '24Dec 22 '24Dec 25 '24Dec 28 '24Dec 31 '24Jan 01 '253.0
|

Author Biographies

Aleksandr Sergeevich Kazachenko, Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center "Krasnoyarsk Scientific Center SB RAS", Siberian Federal University

candidate of chemical sciences, Senior Researcher, Laboratory of Chemistry of Natural Organic Raw Materials

Roman Vladimirovich Borisov , Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center "Krasnoyarsk Scientific Center SB RAS", Siberian Federal University

candidate of chemical sciences, Researcher, Laboratory of Hydrometallurgical Processes

Angelina Viktorovna Miroshnikova , Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center "Krasnoyarsk Scientific Center SB RAS", Siberian Federal University

candidate of chemical sciences, Researcher, Laboratory of Chemistry of Natural Organic Raw Materials

Sergey Viktorovich Baryshnikov , Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center "Krasnoyarsk Scientific Center SB RAS"

candidate of chemical sciences, Senior Researcher, Laboratory of Chemistry of Natural Organic Raw Materials

Olga Sergeevna Selezneva , Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center "Krasnoyarsk Scientific Center SB RAS"

Postgraduate Student, Engineer, Laboratory of Chemistry of Natural Organic Raw

Andrey Mikhailovich Skripnikov , Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center "Krasnoyarsk Scientific Center SB RAS", Siberian Federal University

Junior Researcher, Laboratory of Chemistry of Natural Organic Raw Materials

References

Jindal M., Uniyal P., Thallada B. Bioresource Technology, 2023, vol. 385, 129396.

Zhang Y. et al. Applied Energy, 2015, vol. 150, pp. 128–137.

Zhang X. et al. Applied Energy, 2018, vol. 227, pp. 73–79.

Oh S., Ahn S.-H., Choi J.W. Journal of the Korean Wood Science and Technology, 2019, vol. 47(3), pp. 344–359.

Miroshnikova A.V. et al. Catalysis in Industry, 2022, vol. 14(2), pp. 231–250.

Kuznetsov B.N. et al. Catalysts, 2021, vol. 11, 1362. https://doi.org/10.3390/catal11111362.

Li Y. et al. Angewandte Chemie International Edition, 2023, vol. 62(32), e202307116.

Van den Bosch S. et al. Chemical Communications, 2015, vol. 51(67), pp. 13158–13161.

Zhang K. et al. Bioresource Technology, 2019, vol. 285, 121335.

Van den Bosch S. et al. Energy & Environmental Science, 2015, vol. 8(6), pp. 1748–1763.

Shah A.A. et al. Processes, 2022, vol. 10, 207. https://doi.org/10.3390/pr10020207.

Borisov R.V. et al. Russian Chemical Bulletin, 2022, vol. 71(6), pp. 1164–1172.

Borisov R.V. et al. Inorganic Materials, 2022, vol. 58(2), pp. 215–222.

Borisov R.V., Belousov O.V., Zhizhaev A.M. Russian Journal of Inorganic Chemistry, 2020, vol. 65(10), pp. 1623–1629.

Obolenskaya A.V., Yel'nitskaya Z.P., Leonovich A.A. Laboratornyye raboty po khimii drevesiny i tsellyulozy: uchebnoye posobiye dlya vuzov. [Laboratory work on the chemistry of wood and cellulose: a textbook for universities]. Moscow, 1991, 320 p. (in Russ.).

Sjöström E., Alén R. Analytical Methods in Wood Chemistry, Pulping, and Papermaking. Berlin-Heidelberg: Springer-Verlag, 1999.

Ruiz-Matute A.I. et al. Journal of Chromatography B, 2011, vol. 879(17), pp. 1226–1240.

Werner K., Pommer L., Broström M. Journal of Analytical and Applied Pyrolysis, 2014, vol. 110, pp. 130–137.

Schutyser W. et al. Chemical Society Reviews, 2018, vol. 47(3), pp. 852–908.

Chikunov A.S. et al. J. Sib. Fed. Univ. Chem., 2018, vol. 11(1), pp. 131–150.

Taran O.P. et al. Catalysts, 2022, vol. 12, 1384. https://doi.org/10.3390/catal12111384.

Parsell T. et al. Green Chemistry, 2015, vol. 17(3), pp. 1492–1499.

Published
2024-12-04
How to Cite
1. Kazachenko A. S., Borisov R. V., Miroshnikova A. V., Baryshnikov S. V., Selezneva O. S., Skripnikov A. M. HYDROGENATION OF PINE WOOD IN SUPERCRITICAL ETHANOL WITH IR AND Pd-Ir CATALYSTS // chemistry of plant raw material, 2024. № 4. P. 380-388. URL: http://journal.asu.ru/cw/article/view/15086.
Issue
No 4 (2024)
Section
Technology

Copyright (c) 2024 chemistry of plant raw material

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.

The authors, which are published in this journal, agree to the following conditions:

1. Authors retain the copyright to the work and transfer to the journal the right of the first publication along with the work, at the same time licensing it under the terms of the Creative Commons Attribution License, which allows others to distribute this work with the obligatory indication of the authorship of this work and a link to the original publication in this journal .

2. The authors retain the right to enter into separate, additional contractual agreements for the non-exclusive distribution of the version of the work published by this journal (for example, to place it in the university depository or to publish it in a book), with reference to the original publication in this journal.

3. Authors are allowed to post their work on the Internet (for example, in a university repository or on their personal website) before and during the review process of this journal, as this may lead to a productive discussion, as well as more links to this published work.