HYBRID TI-CONTAINING LIGNOCELLULOSIC POWDERED MATERIAL FROM RECYCLED CARDBOARD
Abstract
Paper’s and cardboard’s wastes are the most frequent and voluminous type of garbage that requires recycling for preservation of ecosystem. In the work on the example of recycled cardboard, the possibility of processing secondary plant raw materials into new useful hybrid lignocellulosic products of powdered type using the system from tetrachloride titanium and hexane (TiCl4-C6H14) was shown. A comparative analysis of hybrid powdered materials from recycled cardboard and wood pulp obtained under equal conditions was carried out. A proportional increase in the mass and ash content of powdered materials was shown with an increase in the amount mmoles of Ti (IV) in the reaction system. Was found that most of the adsorbed on the fibers surface of titanium compounds are readily soluble in an aqueous 10% solution of sulfuric acid, what indicates the possibility of their simple removal, if necessary. Was shown that fractional distribution along the length of fibers considerably narrows after the treatment, the average length decreases to 7,1 times. Was established that the prevailing fraction of all hybrid destructed samples is represented by fibers with a length of 0,12–0,15 mm, regardless of the consumption of Ti (IV), however, in products from cardboard, fraction of that fibers is higher, average dimensional characteristics are less than in products from wood pulp.Downloads
Metrics
References
Yilmaz М. European Journal of Accounting Auditing and Finance Research, 2015, vol. 3, no. 4, pp. 58–68.
Villanueva A., Wenzel H., Strömberg K., Viisimaa M., Skovgaard M. EEA Technical report, 2006, no. 5, 157 р.
Dibakar Bhattacharjee, Md. Kamrul Islam. Proceedings of the 15th Annual Paper Meet., 2014, pp. 1–6. DOI:10.13140/2.1.4078.8802
Vanchakov M.V., Kuleshov A.V., Konovalova G.N. Tekhnologiia i oborudovanie dlia pererabotki makulatury. [Technology and equipment for waste paper processing]. part I, St. Petersburg, 2011, 99 p. (in Russ.).
Palamarchuk N.F., Moroz V. Khimiia rastitel'nogo syr'ia, 2012, no. 3, pp. 193–196. (in Russ.).
Dul'kin D.A., Iuzhaninova L.A., Mironova V.G., Spiridonov V.A. Lesnoi zhurnal, 2005, no. 1-2, pp. 105–123. (in Russ.).
Kuleshov A.V., Smolin A.S. Khimiia rastitel'nogo syr'ia, 2008, no. 2, pp. 109–112. (in Russ.).
Valente M., Tirillò J., Quitadamo A., Santulli C. Composites Part B: Engineering, 2016, vol. 110, pp. 520–529.
Patent 2478664 (RU). (in Russ.).
Patent 2493169 (RU). (in Russ.).
Kuvshinova L.A., Frolova S.V. Butlerov Communications, 2013, vol. 35, no. 7, pp. 109–118.
Kuvshinova L.A., Manahova T.N. Analytic chemistry from laboratory to process line. Apple Academic Press, Part I: Applied chemistry research notes. 2015. Сhapter 7, pp. 35–42. DOI: 10.1201/b19596-9.
Cherezova E.N., Saigitbatalova S.Sh., Kuvshinova L.A., Udoratina E.V. Promyshlennoe proizvodstvo i ispol'zovanie elastomerov, 2014, no. 4, pp. 24–28. (in Russ.).
Svidetel'stvo ob attestatsii № 88-17645-008-Ra.RU.310657-2016. Metodika izmerenii massovoi doli rentgeno-amorfnogo titana v tselliuloznykh i lignotselliuloznykh materialakh, modifitsirovannykh v rastvorakh tetrakhlorida ti-tana. [Certificate of Attestation No. 88-17645-008-Ra.RU.310657-2016. Method for measuring the mass fraction of x-genoamorphic titanium in cellulose and lignocellulosic materials modified in solutions of titanium tetrachloride]. Frolova S.V., Kuvshinova L.A., Kaneva M.V. 2016. 15 с. (in Russ.).
Obolenskaia A.V., El'nitskaia Z.P., Leonovich A.A. Laboratornye raboty po khimii drevesiny i tselliulozy. [Laboratory work on the chemistry of wood and cellulose]. Moscow, 1991, 320 p. (in Russ.).
Rusakova S.M., Artamonova I.V. Izvestiia MGTU «MAMI», 2013, vol. 3, no. 1, pp. 114–115. (in Russ.).
Kuvshinova L.A., Frolova S.V. Struktura i fiziko-khimicheskie svoistva tselliuloz i nanokompozitov na ikh osnove. [Structure and physicochemical properties of celluloses and nanocomposites based on them]. Petrozavodsk, 2014, part 3, pp. 30–97. (in Russ.).
Kuvshinova L.A., Demin V.A. Khimiia i tekhnologiia rastitel'nykh veshchestv. [Chemistry and Technology of Plant Substances]. Syktyvkar, 2005, pp. 24–31. (in Russ.).
Triantafyllou V.I., Akrida-Demertzi K., Demertzis P.G. Food Chemistry, 2007, vol. 101, no. 4, pp. 1759–1768.
Kuvshinova L.A., Manakhova T.N. Khimiia rastitel'nogo syr'ia, 2014, no. 2, pp. 29–34. DOI: 10.14258/jcprm.1402029. (in Russ.).
This work is licensed under a Creative Commons Attribution 4.0 International License.
The authors, which are published in this journal, agree to the following conditions:
1. Authors retain the copyright to the work and transfer to the journal the right of the first publication along with the work, at the same time licensing it under the terms of the Creative Commons Attribution License, which allows others to distribute this work with the obligatory indication of the authorship of this work and a link to the original publication in this journal .
2. The authors retain the right to enter into separate, additional contractual agreements for the non-exclusive distribution of the version of the work published by this journal (for example, to place it in the university depository or to publish it in a book), with reference to the original publication in this journal.
3. Authors are allowed to post their work on the Internet (for example, in a university repository or on their personal website) before and during the review process of this journal, as this may lead to a productive discussion, as well as more links to this published work.
