MONOESTERS 3ʹ,4ʹ-DIHYDROSESELINE OF THE ROOTS OF SESELI CAMPESTRE
Abstract
From the sum of extractive substances of roots of the Seseli campestre collected in phase end of flowering – beginning of fructification by column chromatography two compounds: C19H20O6, m.p. 120,0–121,5 °C (I) and C19H20O6, colorless resin (II) has been isolated. Based on the data obtained at the study of the spectra (I: IR, n, cm-1: 3400, 1719, 1711, 1649, 1604, 1568; NMR 1Н, d, ppm: 1.50, 2СН3; 1,80, СН3–С=; 1,85, J=7,0 Hz, СН3–СН=; 5,10, J=18,38 Hz, Н-4ʹ; 6,10, 2Н; 6,25, J=9,65 Hz, Н-4; 7,95, J=9,65 Hz, Н-3; 7,50, J=8,73 Hz, Н-5; 7,80, J=8,73 Hz, Н-6; II: IR, n, cm-1: 3400, 1718, 1700, 1646, 1602, 1565, 1490; ЯМР 1Н, d, ppm: 1,35, СН3–; 1,70, СН3–; 1,85, (СН3–); 2,10 (СН3–); 4,70, J=14,71 Hz, 5,70; 6,10, J=18,38 Hz; 6,25, J=9,65 Hz, Н-4; 7,95, J=9,65 Hz, Н-3; 7,50, J=8,73 Hz, Н-6; Dept 135 и Dept 90) established that compound I have structure of 3ʹ-angeloiloxy-4ʹ-oxy-3ʹ,4ʹ-dihydroseseline and II – 3ʹ-oxy-4ʹ-senecioiloxy-3ʹ,4ʹ-dihydroseseline.
Downloads
Metrics
References
Кузнецова Г.А., Флоря В.Н. Кумарины из корней, надземной массы и плодов Seseli campestre Bess., произрастающей в Молдавии // ЖПХ, 1970. Т. 43, вып. 6. С. 1412-1414.
Шагова Л.И., Флоря В.Н., Кузнецова Г.А. и др. Диэфиры келлактона и рутарин (кампесенин) из Seseli campestre, произрастающей в Молдавии // Химия природ. соедин. 1973. №5. С. 665-666.
Абышев А.З., Сидоров И.П., Абышев Д.З., Флоря В.Н. и др. Сравнительная характеристика кумаринового состава Seseli campestre, произрастающей в Молдавии и и на Кавказе // Химия природ. соедин. 1982. №4. С. 434-441.
Абышев А.З., Агаев Э.М., Керимов Ю.Б. Химия и фармакология природных кумаринов. Баку, 2003. 112 С.
Черепанов С.К. Сосудистые растения СССР. Л., Наука. 1981. 509 С.
Spath E., Bose P.K., Matzke S. et al. Die cumarine von Seseli indicum und die constitution des Seselins // Ber., 1939. Bol. 72. S. 821-830.
Чернобай В.Т., Колесников Д.Г. Кумарины Жабрицы равнинной (Seseli compestre) // Укр. Ж. 1959. Т. 25, №1. С. 111-113.
Gonzales A.G. Piranocoumarin derivatives from Seseli tortuosum // Phytochemistry. 1979. V. 18, N 6. P. 1021-1023.
This work is licensed under a Creative Commons Attribution 4.0 International License.
The authors, which are published in this journal, agree to the following conditions:
1. Authors retain the copyright to the work and transfer to the journal the right of the first publication along with the work, at the same time licensing it under the terms of the Creative Commons Attribution License, which allows others to distribute this work with the obligatory indication of the authorship of this work and a link to the original publication in this journal .
2. The authors retain the right to enter into separate, additional contractual agreements for the non-exclusive distribution of the version of the work published by this journal (for example, to place it in the university depository or to publish it in a book), with reference to the original publication in this journal.
3. Authors are allowed to post their work on the Internet (for example, in a university repository or on their personal website) before and during the review process of this journal, as this may lead to a productive discussion, as well as more links to this published work.
