STUDIES OF THE ORGANIC ORIGIN CHEMICAL COMPOUNDS OF BROWN COALS AND CARBONIZED PLANT RESIDUES FROM NORTHERN TIMAN

UDC 547.458.82

  • Lyudmila Sergeyevna Kocheva Institute of Geology, Komi Scientific Center, Ural Branch of the RAS Email: karko07@mail.ru
  • Anatoliy Petrovich Karmanov Institute of Biology, Komi Scientific Center, Ural Branch of the RAS; Syktyvkar Forest Institute http://orcid.org/0000-0001-6871-5684 Email: apk0948@yandex.ru
  • Vladimir Pavlovich Lutoev Institute of Geology, Komi Scientific Center, Ural Branch of the RAS Email: vlutoev@geo.komisc.ru
  • Sergey Aleksandrovich Pokryshkin Northern (Arctic) Federal University Email: s.pokryshkin@narfu.ru
DOI_disc_logo https://doi.org/10.14258/jcprm.2020027229
Keywords: brown coal, carbonized plant residues, lignins, physical-chemical research methods, Devonian, Northern Timan

Abstract

The results of the physical and chemical studies of the organic matter of Devonian brown coals and rocks with carbonized plant residues from Northern Timan (Russian Arctic) are presented. We used a complex of physical and chemical methods, including IR spectroscopy, EPR spectroscopy, quantitative chemical analysis, pyrolytic gas chromato-mass spectrometry. For comparative studies we used Devonian (Middle Timan) and Jurassic (Griva, Komi Republic, Russia) carbonized plant residues and lignins, isolated from modern wood and non-wood plants. Organic structures of aromatic nature, which are products of the metamorphic transformation of lignins of coal-forming plants, were found in the investigated samples. It was shown that lignin’s relics show pronounced paramagnetic properties, mainly due to the presence of phenoxyl radicals. The concentration of paramagnetic centers reaches a value that is close to the maximum value nорг for carbonaceous substances. Based on quantitative analysis of phenolic products of pyrolysis the composition of lignin relics was calculated, taking into account the ratio of the main structural H, G and S units. Experimental data allowed to put forward the hypothesis that in the composition of Devonian coal-forming plants, as one of the first representatives of forest communities on the planet, included compositionally homogeneous protolignins of H-type, built mainly from p-coumaric structural units.

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Author Biographies

Lyudmila Sergeyevna Kocheva, Institute of Geology, Komi Scientific Center, Ural Branch of the RAS

руководитель лаборатории

Anatoliy Petrovich Karmanov, Institute of Biology, Komi Scientific Center, Ural Branch of the RAS; Syktyvkar Forest Institute

ведущий научный сотрудник

Vladimir Pavlovich Lutoev, Institute of Geology, Komi Scientific Center, Ural Branch of the RAS

ведущий научный сотрудник

Sergey Aleksandrovich Pokryshkin, Northern (Arctic) Federal University

научный сотрудник

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Published
2020-06-10
How to Cite
1. Kocheva L. S., Karmanov A. P., Lutoev V. P., Pokryshkin S. A. STUDIES OF THE ORGANIC ORIGIN CHEMICAL COMPOUNDS OF BROWN COALS AND CARBONIZED PLANT RESIDUES FROM NORTHERN TIMAN // chemistry of plant raw material, 2020. № 2. P. 55-64. URL: http://journal.asu.ru/cw/article/view/7229.
Issue
No 2 (2020)
Section
Biopolymers of plants

Copyright (c) 2020 сhemistry of plant raw material

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