SEASONAL CHANGES IN THE COMPOSITION OF SCOTS PINE (PINUS SYVESTRIS L.) OLEORESIN MEASURED BY THE NMR METHOD

UDC 543.429.23 : 665.944.54

  • Evgeny Dominikovich Skakovskii Institute of Physical and Organic Chemistry of the National Academy of Sciences of Belarus Email: sed@ifoch.bas-net.by
  • Lyudmila Yul'yevna Tychinskaya Institute of Physical and Organic Chemistry of the National Academy of Sciences of Belarus Email: sed@ifoch.bas-net.by
  • Alena Igorevna Hapankova Institute of Physical and Organic Chemistry of the National Academy of Sciences of Belarus Email: elenagapankova@gmail.com
  • Irina Aleksandrovna Latyshevich Institute of Physical and Organic Chemistry of the National Academy of Sciences of Belarus Email: irinalatyshevich@gmail.com
  • Evgeny Germanovich Popov Central Botanical Garden of the National Academy of Sciences of Belarus Email: ehpopoff@mail.ru
  • Sergey Aleksandrovich Lamotkin Belarusian State Technological University Email: jossby@rambler.ru
DOI_disc_logo https://doi.org/10.14258/jcprm.2022019680
Keywords: Pinus sylvestris L., oleoresin, monoterpenes, resinous acids, NMR, spectrum

Abstract

Analysis of seasonal changes in the composition of Scots pine oleoresin by 1H and 13C NMR spectroscopy was carried out. Due to favorable weather conditions (positive temperatures on the days of sampling throughout the year) samples for each of the 12 months were obtained and studied. Chloroform (CDCl3) solutions of oleoresin were studied. Eight resin acids were identified and quantified: abietic, dehydroabietic, isopimaric, levopimaric, neoabietic, palustric, pimaric and sandaracopymaric, and also 6 monoterpenes: camphene, limonene, myrcene, α-pinene, β-pinene and terpinolene. It was found that the amount of oleoresin and α-pinene contained in it decreased at low temperatures. At the same time other monoterpenes were not detected within the measurement error. It was supposed that monoterpenes formed in smaller amounts during the period of pests' anabiosis, play the main role in the control of coniferous insect pests. It was found that the content of dehydroabietic, isopimaric, neoabietic, pimaric, and sandaracopymaric acids varied insignificantly during the year. The relationship between the amounts of abietic, levopimaric and palustric acids in the composition of oleoresin was found. It was supposed that the observed relationship was caused by low-temperature catalytic reactions of levopimaric acid isomerization with formation of abietic acid mainly. It was suggested that these processes should be taken into account to exclude errors in determining the content of the above acids in oleoresin even in case of statistical analysis.

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Author Biographies

Evgeny Dominikovich Skakovskii, Institute of Physical and Organic Chemistry of the National Academy of Sciences of Belarus

кандидат химических наук, ведущий научный сотрудник лаборатории физико-химических методов исследования

Lyudmila Yul'yevna Tychinskaya, Institute of Physical and Organic Chemistry of the National Academy of Sciences of Belarus

кандидат химических наук, заведующий лабораторией физико-химических методов исследования

Alena Igorevna Hapankova, Institute of Physical and Organic Chemistry of the National Academy of Sciences of Belarus

аспирант, младший научный сотрудник лаборатории мембранных процессов

Irina Aleksandrovna Latyshevich, Institute of Physical and Organic Chemistry of the National Academy of Sciences of Belarus

научный сотрудник лаборатории мембранных процессов

Evgeny Germanovich Popov, Central Botanical Garden of the National Academy of Sciences of Belarus

кандидат биологических наук, ведущий научный сотрудник лаборатории разнообразия растительных ресурсов

Sergey Aleksandrovich Lamotkin, Belarusian State Technological University

кандидат химических наук, доцент кафедры физико-химических методов сертификации продукции

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Published
2022-03-10
How to Cite
1. Skakovskii E. D., Tychinskaya L. Y., Hapankova A. I., Latyshevich I. A., Popov E. G., Lamotkin S. A. SEASONAL CHANGES IN THE COMPOSITION OF SCOTS PINE (PINUS SYVESTRIS L.) OLEORESIN MEASURED BY THE NMR METHOD // chemistry of plant raw material, 2022. № 1. P. 193-202. URL: http://journal.asu.ru/cw/article/view/9680.
Issue
No 1 (2022)
Section
Low-molecular weight compounds

Copyright (c) 2022 chemistry of plant raw material

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