THE OXIDATIVE TREATMENT INFLUENCE ON THE PROPERTIES OF CARBON MATERIALS OBTAINED FROM MICROCRYSTAL CELLULOSE

  • Надежда Михайловна Микова Institute of Chemistry and Chemical Technology SB RAS, Krasnoyarsk Email: nm@icct.ru
  • Иван Петрович Иванов Institute of Chemistry and Chemical Technology SB RAS, Krasnoyarsk Email: ivanov@icct.ru
  • Николай Васильевич Чесноков Institute of Chemistry and Chemical Technology SB RAS, Krasnoyarsk; Krasnoyarsk Scientific Centre SB RAS, Akademgorodok, 50, Krasnoyarsk, 660036 Email: cnv@icct.ru
  • Валерий Федорович Каргин Institute of Chemistry and Chemical Technology SB RAS, Krasnoyarsk Email: kargin@icct.ru
DOI_disc_logo https://doi.org/10.14258/jcprm.1402051
Keywords: microcrystal cellulose, carbonization, oxidative modification, surface groups, adsorption and catalytic properties

Abstract

The surface modification of carbonized at 450 °C microcrystal cellulose (MCC-450) by the oxidative agents solutions of different strength: 30% H2O2, 3N H2SO4, oleum and chlorosulfonic acid HSO3Cl results in preparation of carbon materials (CM) with different degrees of surface oxidation. The obtained CM were characterized using FTIR, BET, elemental and X-ray spectral analyses. The obtained results showed that more carboxylic and hydroxyl surface oxygen groups were introduced into CM composition as a result of oleum and HSO3Cl oxidation process than by the oxidative solutions of Н2О2 и 3N H2SO4. Significant quality of surface oxygen in the MCC/oleum and MCC/HSO3Cl samples is part of НSO3- groups, where the S content was 2,3–2,5% at. It has been found that oxidized sample MCC/oleum reveals activity in test reactions of cellulose catalytic hydrolysis and esterification of acetic acid with ethanol.

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Author Biographies

Надежда Михайловна Микова, Institute of Chemistry and Chemical Technology SB RAS, Krasnoyarsk
старший научный сотрудник, кандидат химических наук, тел.: (391) 249-53-87
Иван Петрович Иванов, Institute of Chemistry and Chemical Technology SB RAS, Krasnoyarsk
старший научный сотрудник, кандидат технических наук, тел.: (391) 249-48-94
Николай Васильевич Чесноков, Institute of Chemistry and Chemical Technology SB RAS, Krasnoyarsk; Krasnoyarsk Scientific Centre SB RAS, Akademgorodok, 50, Krasnoyarsk, 660036
заместитель директора Института химии и химической технологии СО РАН, заместитель председателя Красноярского научного центра СО РАН, доктор химических наук, тел.: (391) 249-53-99
Валерий Федорович Каргин, Institute of Chemistry and Chemical Technology SB RAS, Krasnoyarsk
старший научный сотрудник, кандидат химических наук, тел.: (391) 249-55-87

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Published
2014-06-10
How to Cite
1. Микова Н. М., Иванов И. П., Чесноков Н. В., Каргин В. Ф. THE OXIDATIVE TREATMENT INFLUENCE ON THE PROPERTIES OF CARBON MATERIALS OBTAINED FROM MICROCRYSTAL CELLULOSE // chemistry of plant raw material, 2014. № 2. P. 51-59. URL: http://journal.asu.ru/cw/article/view/jcprm.1402051.
Issue
No 2 (2014)
Section
Biopolymers of plants

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