THE STUDY OF CHEMICAL AND TECHNOLOGICAL PROPERTIES OF THE ETHANOL EXTRACT OF PINE OBTAINED FROM DEBARKING AND ITS POSSIBLE APPLICATION IN THE LEATHER AND FUR INDUSTRY
Abstract
This paper investigated the effect of ethanol on the quality of the extract of pine produced from low-grade raw materials and their processing properties. We studied the relationship between views of the extractant and the degree of modification of collagen - the main skins' protein by simulating the process of tanning. The products of dissolution of collagen (PDC) treated with ethyl extract of pine were used as the model. The degree of modification was determined by differential scanning calorimetry. The investigations revealed that the alcohol extract of pine features a large tar content and a high degree of purity (~92,6%). Interaction between extractives and collagen goes mainly on amide nitrogen and the side carboxyl groups, with ε-amino groups and phenolic hydroxyl groups - that have probably been blocked by hydrogen bondsare – are being released. Heat resistance of coats derived from the tanned PDC is high enough, it can be concluded that there may be the possible use of alcohol extracts of pine in the leather and fur industry as a tanning agent.
Downloads
Metrics
References
Страхов И.П., Шестакова И.С., Куциди Д.А. и др. Химия и технология кожи и меха / под ред. проф. И.П. Страхова. 3-е изд. перераб. и доп. М., 1979. 504 с.
Дейнеко И.П., Дейнеко Л.П., Белов Л.П. Исследование химического состава коры сосны // Химия раститель-ного сырья. 2007. №1. С. 19–24.
Рязанова Т.В., Репях С.М. Химия и технология коры хвойных : монография: в 2 ч. Ч. 1: Химия и использова-ние коры. Красноярск, 2010. 160 с.
ГОСТ 28508-90. Экстракты дубильные растительные. Методы определения. М., 1990.
Гончарова Н.В., Сячинова Н.В., Думнова Е.А. Изучение влияния природы экстрагента на качественные ха-рактеристики сосновых экстрактов // Кожа и мех в XXI веке: технология, качество, экология образование : материалы V Междун. научно-практической конференции. Улан-Удэ, 2009. С. 68–73.
Гончарова Н.В. Растительные экстракты: комплексный анализ : методические указания по курсу «Химия и тех-нология кожи и меха» для студентов специальности 260904 «Технология кожи и меха». Улан-Удэ, 2011. 83 с.
Аналитические методы белковой химии. М., 1963. 309 с.
Уэндландт У. Термические методы анализа. М., 1978, 526 с.
Пилоян Г.О., Новикова О.С. Вычисление кинетических параметров по данным дериватографических измере-ний // Журнал неорганической химии. 1967. Вып. 12. С. 602–605.
This work is licensed under a Creative Commons Attribution 4.0 International License.
The authors, which are published in this journal, agree to the following conditions:
1. Authors retain the copyright to the work and transfer to the journal the right of the first publication along with the work, at the same time licensing it under the terms of the Creative Commons Attribution License, which allows others to distribute this work with the obligatory indication of the authorship of this work and a link to the original publication in this journal .
2. The authors retain the right to enter into separate, additional contractual agreements for the non-exclusive distribution of the version of the work published by this journal (for example, to place it in the university depository or to publish it in a book), with reference to the original publication in this journal.
3. Authors are allowed to post their work on the Internet (for example, in a university repository or on their personal website) before and during the review process of this journal, as this may lead to a productive discussion, as well as more links to this published work.