INVESTIGATION OF MECHANICAL PROPERTIES, MORPHOLOGY, AND BIODEGRADABILITY OF COMPOSITIONS BASED ON POLYLACTIDE AND POLYSACCHARIDES

  • Светлана (Svetlana) Захаровна (Zaharovna) Роговина (Rogovina) Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991 Email: s.rogovina@mail.ru
  • Кристине (Kristine) Владимировна (Vladimirovna) Алексанян (Aleksanyan) Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991 Email: aleksanyan.kristine@gmail.com
  • Аркадий (Arkadij) Яковлевич (Jakovlevich) Горенберг (Gorenberg) Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991 Email: s.rogovina@mail.ru
  • Юлия (Julija) Ивановна (Ivanovna) Дерябина (Deryabina) Baсh Institute of Biochemistry, Russian Academy of Sciences, Leninskii pr. 33, build. 2, Moscow, 119071 Email: s.rogovina@mail.ru
  • Елена (Elena) Павловна (Pavlovna) Исакова (Isakova) Baсh Institute of Biochemistry, Russian Academy of Sciences, Leninskii pr. 33, build. 2, Moscow, 119071 Email: s.rogovina@mail.ru
  • Эдуард (Eduard) Вениаминович (Veniaminovich) Прут (Prut) Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991 Email: evprut@chph.ras.ru
  • Александр (Aleksandr) Александрович (Aleksandrovich) Берлин (Berlin) Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991 Email: berlin@chph.ras.ru
Keywords: biodegradability, blend, ethyl celluloseа, chitosan, polylactide, poly(ethylene glycol)

Abstract

The blends of polylactide with ethyl cellulose and chitosan are obtained in a Brabender mixer under conditions of high temperature shear deformations at different initials ratios of reagents. The investigation of physicomechanical properties of compositions has shown that systems have high rigidity. To improve the elasticity poly(ethylene glycol) (PEG) and high-molecular polyolefin polydecene are added into compositions. It has turned out that polydecene weakly affects the mechanical characteristics, while PEG leads to noticeable increase in elongation at break. Biodegradability of compositions obtained is investigated by weight loss of samples after holding in soil, tests on fungus resistance, and analysis of film morphology by scanning electron microscopy after holding in soil. It is found that introduction of third component (PEG) leads to increase in composition biodegradability.

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Author Biographies

Светлана (Svetlana) Захаровна (Zaharovna) Роговина (Rogovina), Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991
Доктор химических наук, профессор, ведущий научный сотрудник
Кристине (Kristine) Владимировна (Vladimirovna) Алексанян (Aleksanyan), Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991
старший научный сотрудник, кандидат  химических наук, тел. (8-495) 939-71-55
Аркадий (Arkadij) Яковлевич (Jakovlevich) Горенберг (Gorenberg), Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991
старший научный сотрудник, кандидат  химических наук, тел. (8-495) 939-71-75
Юлия (Julija) Ивановна (Ivanovna) Дерябина (Deryabina), Baсh Institute of Biochemistry, Russian Academy of Sciences, Leninskii pr. 33, build. 2, Moscow, 119071
заведующая лабораторией, кандидат биологических наук, тел. (8-495) 954-40-88
Елена (Elena) Павловна (Pavlovna) Исакова (Isakova), Baсh Institute of Biochemistry, Russian Academy of Sciences, Leninskii pr. 33, build. 2, Moscow, 119071
старший научный сотрудник, кандидат биологических наук, тел. (8-495) 954-40-88
Эдуард (Eduard) Вениаминович (Veniaminovich) Прут (Prut), Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991
заведующий лабораторией, доктор химических наук, профессор, тел. (8-495) 939-71-55
Александр (Aleksandr) Александрович (Aleksandrovich) Берлин (Berlin), Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991
директор института, академик РАН, тел. (8-495) 939-72-49

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Published
2014-12-22
How to Cite
1. Роговина (Rogovina)С. (Svetlana) З. (Zaharovna), Алексанян (Aleksanyan)К. (Kristine) В. (Vladimirovna), Горенберг (Gorenberg)А. (Arkadij) Я. (Jakovlevich), Дерябина (Deryabina)Ю. (Julija) И. (Ivanovna), Исакова (Isakova)Е. (Elena) П. (Pavlovna), Прут (Prut)Э. (Eduard) В. (Veniaminovich), Берлин (Berlin)А. (Aleksandr) А. (Aleksandrovich) INVESTIGATION OF MECHANICAL PROPERTIES, MORPHOLOGY, AND BIODEGRADABILITY OF COMPOSITIONS BASED ON POLYLACTIDE AND POLYSACCHARIDES // chemistry of plant raw material, 2014. № 1. P. 29-39. URL: http://journal.asu.ru/cw/article/view/464.
Section
Biopolymers of plants