EXTRACTION OF Al3+, Pb2+, Cd2+ AND Sr2+ IONS WITH A PHOSPHORUS-CONTAINING PRODUCT FROM RICE FLOUR
UDC 542.06 : 661.887: 664.782.86
Abstract
Materials of natural origin can serve as raw materials for the production of environmentally friendly inexpensive polyfunctional materials with a wide range of applications. Agricultural waste from rice production (rice husks, straw and flour) can serve as a source of such substances. In this work, the process and conditions for the extraction of aluminum, lead, strontium and cadmium ions from aqueous solutions by an organophosphorus product (derivative of inositol hexaphosphoric, phytic acid) obtained from rice flour production waste are studied. Phytic acid and its derivatives are highly effective ligands capable of chelating metal cations, which allows them to be considered as a natural material suitable for removing heavy metal ions from aqueous solutions. The degree of extraction of aluminum ions reaches 97%, lead and strontium – 89%, and cadmium – 93%. It is shown that the absorption decreases in the series Cr3+ > Al3+ > Bi3+ (from 13.0 mg/g to 4.9 mg/g) and Cd2+ > Pb2+ > Sr2+ (from 8.9 mg/g to 7.5 mg/g). These studies allow us to offer a fundamental possibility of using a natural phosphorus-containing compound as an environmentally friendly sorbent.
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Vodyanitskiy Yu.N. Tyazhelyye i sverkhtyazhelyye metally i metalloidy v zagryaznennykh pochvakh. [Heavy and su-perheavy metals and metalloids in contaminated soils]. Moscow, 2009, 95 p. (in Russ.).
Putilina V.S., Galitskaya I.V., Yuganova T.I. Ekologiya, 2013, no. 101, p. 95. (in Russ.).
Shugaley I.V., Garabadzhiu A.V., Ilyushin M.A., Sudarikov A.M. Ekologicheskaya khimiya, 2012, vol. 21, pp. 172–186. (in Russ.).
Matevosova K.L., Gryaznova V.A., Chazov T.K. Otkhody i resursy, 2019, vol. 6, no. 2. DOI: 10.15862/11ECOR219. (in Russ.).
Forbes W.F., Gentleman J.F. Experimental Gerontology, 1998, vol. 33, pp. 141–154. DOI: 10.1016/s0531-5565(97)00061-2.
Speranskaya O.A. Obzor problemy zagryazneniya kadmiyem, svintsom i rtut'yu okruzhayushchey sredy v Rossii i na Ukraine. [Overview of the problem of environmental pollution by cadmium, lead and mercury in Russia and Ukraine]. 2008, 59 p. (in Russ.).
WHO Technical Report Series. Evaluation of certain food additives and contaminants (73rd report of the Joint FAO/WHO Expert Committee on Food Additives). 2011, vol. 960, 237 p.
GOST 17.4.1.02-83. Okhrana prirody. Pochvy. Klassifikatsiya khimicheskikh veshchestv dlya kontrolya zagryazneniya. [GOST 17.4.1.02-83. Protection of Nature. Soils. Classification of chemicals for pollution control]. Moscow, 2008, 4 p. (in Russ.).
Dobrovol'skiy V.V. Pochvovedeniye, 2006, no. 11, pp. 1315–1321. (in Russ.).
Lavrishchev A.V., Litvinovich A.V. Stabil'nyy strontsiy v agroekosistemakh. [Stable strontium in agroecosystems]. St. Petersburg, 2019, 192 p. (in Russ.).
Shaheen S.M., Eissa F.I., Ghanem K.M., El-Din H.M.G., Al Anany F.S. Journal of Environmental Management, 2013, vol. 128, pp. 514–521. DOI: 10.1016/j.jenvman.2013.05.061.
Lindholm-Lehto P.C. BioResources, 2019, vol. 14, pp. 4952–4995. DOI: 10.15376/biores.14.2.
Ngah W.S.W., Hanafiah M.A.K.M. Bioresource Technology, 2008, vol. 99, pp. 3935–3948. DOI: 10.1016/j.biortech.2007.06.011.
Bascetin E., Atun G. Journal of Chemical & Engineering Data, 2010, vol. 55, pp. 783–788. DOI: 10.1021/je9004678.
Merceille A., Weinzaepfel E., Barre Y., Grandjean A. Separation and Purification Technology, 2012, vol. 96, pp. 81–88. DOI: 10.1016/j.seppur.2012.05.018.
Mohammadloo H.E., Sarabi A.A. Progress in Organic Coatings, 2016, vol. 101, pp. 391–399. DOI: 10.1016/j.porgcoat.2016.09.009.
Kolzunova L.G., Zemnukhova L.A., Fedorishcheva G.A., Kurilenko L.N., Sergiyenko V.I. Zhurnal prikladnoy khimii, 2000, vol. 73, no. 10, pp. 1644–1651. (in Russ.).
Makarenko N.V., Kharchenko U.V., Slobodyuk A.B., Zemnukhova L.A. Khimiya rastitel'nogo syr'ya, 2013, no. 3, pp. 255–260. DOI: 10.14258/jcprm.1303255. (in Russ.).
Makarenko N.V., Zemnukhova L.A., Nemtarev A.V., Kovekhova A.V., Arefieva O.D. BioResources, 2018, vol. 13, pp. 3411–3419. DOI: 10.15376/biores.13.2.3411-3419.
Makarenko N.V., Arefieva O.D., Kovekhova A.V., Zemnukhova L.A. BioResources, 2019, vol. 14, pp. 4866–4872. DOI: 10.15376/biores.14.2.4866-4872.
Aref'yeva O.D., Makarenko N.V., Yegorkin V.S., Zemnukhova L.A., Azarova Yu.A. Khimiya rastitel'nogo syr'ya, 2021, no. 1, pp. 345–352. DOI: 10.14258/jcprm.2021017751. (in Russ.).
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