SORPTION ABILITY OF SAMPLES OF HUMIC ACIDS AND THEIR SODIUM SALTS WITH RESPECT TO Cd2+ IONS

UDC 544.723.23

Keywords: humic acids, sorbents, sorbtive, toxicants, adsorption effects, degree of extraction

Abstract

The paper presents an analysis of the sorption properties of humic acids and their sodium salts isolated from high-moor peat of the Arkhangelsk region with respect to Cd2+ ions at various pH values. Using adsorption isotherms, the volumetric capacity of the studied preparations was calculated. Langmuir and Freindlich mathematical models were used to quantify the sorption capacity of preparations. Calculation of mathematical models of Langmuir and Freindlich sorption, as well as statistical data processing was carried out using Microsoft Office for Windows, Excel, 2016 software. their sodium salts. An estimate of the rate of binding of cadmium ions by various sorbents is given, and the pH at which the sorption capacity of humic acids and their sodium salts is maximum is determined. The structural and functional features of humic acids are presented, proving their high binding capacity and strength of Cd2+ binding, as well as relatively high selectivity. Based on the results obtained, it is assumed that it is possible to develop and use preparations based on humic acids as sorbents.

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Author Biographies

Tat'yana Aleksandrovna Korel'skaya, Northern State Medical University

кандидат химических наук, доцент, доцент кафедры общей и биоорганической химии

Ekaterina Aleksandrovna Zhuravleva, Northern State Medical University

кандидат биологических наук, доцент кафедры общей и биоорганической химии

Elena Anatolievna Ayvazova, Northern State Medical University

кандидат биологических наук, доцент, заведующая кафедрой общей и биоорганической химии

Natal'ya Aleksandrovna Onokhina, Northern State Medical University

кандидат химических наук, доцент, доцент кафедры общей и биоорганической химии

Natal'ya Aleksandrovna Zubova, Northern State Medical University

кандидат химических наук, старший преподаватель кафедры общей и биоорганической химии

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Published
2023-03-13
How to Cite
1. Korel’skaya T. A., Zhuravleva E. A., Ayvazova E. A., Onokhina N. A., Zubova N. A. SORPTION ABILITY OF SAMPLES OF HUMIC ACIDS AND THEIR SODIUM SALTS WITH RESPECT TO Cd2+ IONS // chemistry of plant raw material, 2023. № 1. P. 333-341. URL: http://journal.asu.ru/cw/article/view/11391.
Section
Peat and products of its processing