INDIRECT ELECTROCATALYTIC OXIDATION OF STARCH BY REACTIVE OXYGEN SPECIES IN SITU GENER-ATED ON Pb/PbO2 ANODE AND BORON-DOPED DIAMOND ELECTRODE IN AQUEOUS ELECTROLYTES

UDC 541.135:547.0

  • Galina Vasil'yevna Kornienko Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS Email: kornienko@icct.ru
  • Svetlana Nikolayevna Kapaeva Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS Email: Sveta0480@inbox.ru
  • Vasiliy Leont'yevich Kornienko Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS Email: kvl@icct.ru
  • Andrey Mikhaylovich Skripnikov Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS; Siberian Federal University Email: And-skripnikov@yandex.ru
  • Oksana Pavlovna Taran Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS; Siberian Federal University Email: taran.op@icct.krasn.ru
DOI_disc_logo https://doi.org/10.14258/jcprm.20220412022
Keywords: electrocatalytic oxidation, potato starch, starch dialdehyde

Abstract

The indirect electrocatalytic oxidation of starch by reactive oxygen species (ROS) generated in situ on lead dioxide anodes and a boron-doped diamond electrode in an acidic aqueous electrolyte has been studied. The influence of the current density, concentration and state of aggregation of the reagent, the scheme of introduction of ROS on the kinetics and yields of the product of indirect oxidation of starch dialdehyde karazmal has been established. The optimal conditions for obtaining oxidized starch were determined: anode – Pb/PbO2, current density – 25 mA/cm-2, electrolyte pH 2–3, electrolysis time – 80 min, 25 °C. Starch oxidation products were analyzed by the following methods: spectrophotometry after deratization with dinitrophenylidrazine, gas chromatography-mass spectrometry after hydrolysis and silylation, and IR spectroscopy. Glucose tautomers, as well as ethylene glycol oligomers, were found in the hydrolyzates of the reaction products by GCMS, indicating the breaking of C-C bonds in the monosaccharide units during the oxidation process.

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Author Biographies

Galina Vasil'yevna Kornienko, Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS

кандидат химических наук, старший научный сотрудник

Svetlana Nikolayevna Kapaeva, Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS

младший научный сотрудник

Vasiliy Leont'yevich Kornienko, Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS

доктор химических наук, ведущий научный сотрудник

Andrey Mikhaylovich Skripnikov, Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS; Siberian Federal University

младший научный сотрудник

Oksana Pavlovna Taran, Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS; Siberian Federal University

доктор химических наук, директор

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Published
2022-12-15
How to Cite
1. Kornienko G. V., Kapaeva S. N., Kornienko V. L., Skripnikov A. M., Taran O. P. INDIRECT ELECTROCATALYTIC OXIDATION OF STARCH BY REACTIVE OXYGEN SPECIES IN SITU GENER-ATED ON Pb/PbO2 ANODE AND BORON-DOPED DIAMOND ELECTRODE IN AQUEOUS ELECTROLYTES // chemistry of plant raw material, 2022. № 4. P. 77-88. URL: http://journal.asu.ru/cw/article/view/12022.
Issue
No 4 (2022)
Section
Biopolymers of plants

Copyright (c) 2022 chemistry of plant raw material

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