OPTIMIZATION OF PECTIN EXTRACTION FROM THE BARK OF SIBERIAN FIR (ABIES SIBÍRICA), CORRUPTED BY USSURI POLYGRAPH (POLYGRAPHUS PROXIMUS)

UDC 54.056/661.123

  • Vladislav Aleksandrovich Ionin Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS; Siberian Federal University Email: ionin.va@icct.krasn.ru
  • Yuriy Nikolayevich Malyar Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS; Siberian Federal University Email: yumalyar@gmail.com
  • Dmitriy Valer'yevich Zimonin Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS; Siberian Federal University Email: zimonind89@mail.ru
  • Valentina Sergeyevna Borovkova Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS; Siberian Federal University Email: bing0015@mail.ru
  • Anna Vasil'yevna Zaharchenko Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS Email: anulechka062@gmail.com
  • Yuliya Aleksandrovna Litovka Sukachev Institute of Forest SB RAS, FRC KSC SB RAS
  • Oksana Pavlovna Taran Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS; Siberian Federal University
  • Igor' Nikolayevich Pavlov Sukachev Institute of Forest SB RAS, FRC KSC SB RAS
Keywords: bark, Abies sibirica Ledeb, Polygraphus proximus Blandford, extractive substances, optimization, antioxidative activity

Abstract

Species of Abies trees are considered susceptible to the effects of diseases and pests. As a result of the complex biotic impact of the Ussuri Polygraph (Polygraphus proximus Blandford) the area of potential drying of Siberian fir (Abies sibirica Ledeb) stands up to 10 million hectares. Trees corrupted by root pathogens are a center of desiccation, from where pathological decay spreads, so also there arise an urgent issue of disposal of corrupted bark and wood waste. A promising solution to this problem is the extractive processing of wood-bark wastes aimed to obtain a wide range of high-valued substances. Fractions of resinous substances, tannins and pectins were isolated from the corrupted A. sibirica bark using the sequential extraction method. The optimization of the process of pectin extraction - one of the most valuable secondary extractive components was carried out. The optimal experimental conditions were established with the highest yield of pectins up to 8.4 wt.%, which is achieved by treating the A. sibirica bark, corrupted by P. proximus, with a HCl solution at pH = 1.71 and the process duration 48 min. The isolated extractive substances (tannins, pectins) from the A. sibirica bark characterized by IR spectroscopy and gel permeation chromatography. The antioxidant activity of tannins and pectins studied using compounds imitated free radicals (1,1-diphenyl-2-picrylhydrazyl), which amounted to 97% and 89%, respectively.

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Author Biographies

Vladislav Aleksandrovich Ionin, Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS; Siberian Federal University

младший научный сотрудник лаборатории каталитических превращений возобновляемых ресурсов

Yuriy Nikolayevich Malyar, Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS; Siberian Federal University

кандидат химических наук, старший научный сотрудник лаборатории каталитических превращений возобновляемых ресурсов

Dmitriy Valer'yevich Zimonin, Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS; Siberian Federal University

кандидат химических наук, научный сотрудник лаборатории молекулярной спектроскопии и анализа

Valentina Sergeyevna Borovkova, Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS; Siberian Federal University

младший научный сотрудник лаборатории каталитических превращений возобновляемых ресурсов

Anna Vasil'yevna Zaharchenko, Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS

ученица класса РАН

Yuliya Aleksandrovna Litovka, Sukachev Institute of Forest SB RAS, FRC KSC SB RAS

доктор биологических наук, старший научный сотрудник лаборатории лесных культур, микологии и фитопатологии

Oksana Pavlovna Taran, Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS; Siberian Federal University

доктор химических наук, профессор, директор

Igor' Nikolayevich Pavlov, Sukachev Institute of Forest SB RAS, FRC KSC SB RAS

доктор биологических наук, профессор, заведующий лабораторией лесных культур, микологии и фитопатологии

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Published
2022-12-15
How to Cite
1. Ionin V. A., Malyar Y. N., Zimonin D. V., Borovkova V. S., Zaharchenko A. V., Litovka Y. A., Taran O. P., Pavlov I. N. OPTIMIZATION OF PECTIN EXTRACTION FROM THE BARK OF SIBERIAN FIR (ABIES SIBÍRICA), CORRUPTED BY USSURI POLYGRAPH (POLYGRAPHUS PROXIMUS) // chemistry of plant raw material, 2022. № 4. P. 67-76. URL: http://journal.asu.ru/cw/article/view/12027.
Section
Biopolymers of plants