INFLUENCE OF PROCESSING CONDITIONS ON OUTPUT AND PRODUCT COMPOSITION OF WHEAT STRAW FRACTIONATION IN MEDIUM 1-BUTYL-3-METHYLIMIDAZOLIUM CHLORIDE

  • Сергей (Sergei) Николаевич (Nikolaevich) Евстафьев (Evstaf'ev) Irkutsk National Research Technical University, ul. Lermontova, 83, Irkutsk, 664074 (Russia) Email: hqc9189@gmail.com
  • Кыонг Хоанг Куанг Irkutsk National Research Technical University, ul. Lermontova, 83, Irkutsk, 664074 (Russia) Email: quangcuong2205@gmail.com

Abstract

The work is devoted to identifying the influence of temperature and duration of wheat straw treatment in the environment chloride 1-butyl-3-methylimidazolium on outputs and composition of the fractions of its main components. It is found that with increasing treatment temperature and duration in the range 100–150 °C cellulose purification occurs by hemicelluloses and lignin. It was revealed that delignification processes occur quite rapidly at 120 °C. As part of the cellulose, fraction of lignin content is reduced to 17–18%, and the strength of hydrogen bonds is broken. All this together it leads to significantly increase the reaction capability cellulose in conditions of enzymatic hydrolysis.

The maximum yield of sugars from polysaccharides of wheat straw (60,8% on the A.S.M.) is obtained after the treatment in a medium chloride 1-butyl-3-methylimidazolium at 140 °C for 2 h.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

Author Biographies

Сергей (Sergei) Николаевич (Nikolaevich) Евстафьев (Evstaf'ev), Irkutsk National Research Technical University, ul. Lermontova, 83, Irkutsk, 664074 (Russia)
Doctor of Chemical Sciences, Professor, Director
Кыонг Хоанг Куанг, Irkutsk National Research Technical University, ul. Lermontova, 83, Irkutsk, 664074 (Russia)
postgraduate

References

Tan S.S.Y., Macfarlane D.R. Top Curr Chem., 2010, vol. 290, pp. 311–339.

Swatloski R.P., Spear S.K., Holbrey J.D., Rogers R.D. J. Am. Chem. Soc., 2002, vol. 124, pp. 4974–4975.

Zhang H., Wu J., Zhang J., He J. Macromolecules, 2005, vol. 3, no. 20, pp. 8272–8277.

Gericke M., Fardim P., Heinze T. Molecules, 2012, vol. 17, pp.7458–7502.

Da Costa Lopes A.M., Joao K.G., Rubik D.F., Bogel-Lukasik E., Duarte L.C., Andreaus J., Bogel-Lukasik R. Bioresour. Technol., 2013, vol. 142, pp. 198–208.

Zhang Zhi-guo, Chen Hong-zhang. African Journal of Biotechnology, 2012, vol. 11, no. 31, pp. 8032–8037.

Dubois M., Gilles K.A. Analyt. Chem., 1956, vol. 28, pp. 350–356.

Zakis G.F. Funktsional'nyi analiz ligninov i ikh proizvodnykh. [Functional analysis of lignins and their derivatives]. Riga, 1987, 230 p. (in Russ.).

Haseth J.K. Decrystallization of lignocellulose biomass using ionic liquids: Master thesis. NTNU, 2012. 85 p.

Faulon J., Carlson G.A., Hatcher P.G. Organic Geochemistry, 1994, vol. 21, pp. 1169–1179.

Lora J.H., Glasser W.G. J. of Polym. and the Environment, 2002, vol. 10, no. 1/2, pp. 39–48.

Pimentel D., Mak-Klelan O. Vodorodnaia sviaz'. [Hydrogen bond]. Moscow, 1964, 462 p. (in Russ.).

Karlivan V.P. Metody issledovaniia tselliulozy. [Methods of cellulose research]. Riga, 1981, 257 p. (in Russ.).

Published
2016-06-29
How to Cite
1. Евстафьев (Evstaf’ev)С. (Sergei) Н. (Nikolaevich), Хоанг Куанг К. INFLUENCE OF PROCESSING CONDITIONS ON OUTPUT AND PRODUCT COMPOSITION OF WHEAT STRAW FRACTIONATION IN MEDIUM 1-BUTYL-3-METHYLIMIDAZOLIUM CHLORIDE // chemistry of plant raw material, 2016. № 4. P. 27-34. URL: http://journal.asu.ru/cw/article/view/1308.
Section
Biopolymers of plants