STUDYING THE PHYSICAL AND CHEMICAL PROPERTIES OF SOLUTIONS OF CARBOXYMETHYLATED PINE WOOD

UDC 630*861

  • Elena Vladimirovna Kalyuta Altai State Agrarian University Email: kalyuta75@mail.ru
  • Vadim Ivanovich Markin Altai State University https://orcid.org/0000-0002-4853-9350 Email: markin@chemwood.asu.ru
  • Mikhail Ilyich Maltsev Altai State Agrarian University Email: uoshs@mail.ru
  • Marina Yuryevna Cheprasova Altai State University Email: marinacheprasova@yandex.ru
Keywords: carboxymethylated pine wood (CMD), viscosity, surface tension, rheological coefficients, rotational viscometry, adjuvants

Abstract

The physicochemical properties (pH, electrical conductivity, relative viscosity, and surface tension) of carboxymethylated wood solutions were studied. It was found that CMD solutions have an alkaline environment, low viscosity, and weaker intra- and intermolecular interactions than solutions of its structural analogue (CMC). The effect of mechanical action on intermolecular interactions and the strength of structural formations in CMD solutions was estimated using rotational viscometry in the shear rate range of 10–000 s-1 and at a temperature of 20 to 50 °C. It was shown that stable rheological behavior of the studied preparation was observed at a concentration of 0.1% in the temperature range of 20–40 °C. At this concentration, the CMD preparation exhibits surface-active properties similar to those of the industrial preparation Neon 99 and can be used as an adjuvant in pesticide treatment of plants.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

Author Biographies

Elena Vladimirovna Kalyuta , Altai State Agrarian University

Associate Professor of the Department of Soil Science and Agrochemistry, Candidate of Chemical Sciences

Vadim Ivanovich Markin, Altai State University

Associate Professor of the Department of Organic Chemistry, Candidate of Chemical Sciences

Mikhail Ilyich Maltsev, Altai State Agrarian University

Head of the Department of General Agriculture and Plant Growing, Candidate of Agricultural Sciences

Marina Yuryevna Cheprasova , Altai State University

Associate Professor of the Department of Organic Chemistry, Candidate of Chemical Sciences

References

Manuilov V.M., Shcherbinina Z.A. Siberian Bulletin of Agricultural Science, 2013, no. 6, pp. 5–10. (in Russ.)

Kotlyarov D.V., Kotlyarov V.V., Fedulov YU.P. Fiziologicheski aktivnyye veshchestva v agrotekhnologiyakh. [Physio-logically active substances in agricultural technologies], Krasnodar, 2016. 224 p. (in Russ.).

Medvedeva A. Vse ob ad"yuvantakh. Agro KHKHI. [All about adjuvants. Agro XXI]. 27.07.2017 [Electronic resource]. URL: https://www.agroxxi.ru/gazeta-zaschita-rastenii/zrast/vse-ob-adyuvantah.html. (in Russ.).

Medvedeva A. Perspektivy rynka sel'skokhozyaystvennykh ad"yuvantov v sleduyushchuyu desyatiletku optimistichny Agro XXI. [Prospects for the agricultural adjuvants market in the next decade are optimistic Agro XXI] 27.04.2023 [Electronic resource]. URL: https://www.agroxxi.ru/gazeta-zaschita-rastenii/novosti/perspektivy-rynka-selskohozjaistvennyh-adyuvantov-v-sleduyuschuyu-desjatiletku-optimistichny.html. (in Russ.).

Voshedskiy N.N. Materialy Mezhdunarodnoy nauchno-prakticheskoy konferentsii «Nauchnoye obespecheniye agropro-myshlennogo kompleksa na sovremennom etape». [Proceedings of the International scientific and practical conference "Scientific support of the agro-industrial complex at the present stage"]. YUFU, 2015, pp. 266–275. (in Russ.).

Zakharenko V.A. Vestnik zashchity rasteniy, 2001, no. 1, pp. 3–17. (in Russ.).

Kalyuta Ye.V., Mal'tsev M.I., Bazarnova N.G. Teoreticheskaya i prikladnaya ekologiya, 2022, no. 1, pp. 175–181. DOI 10.25750/1995-4301-2022-1-175-181. (in Russ.).

Mal'tsev M.I., Kalyuta Ye.V., Markin V.I., Katrakov I.B. Khimiya rastitel'nogo syr'ya, 2019, no. 3, pp. 355–362. DOI: 10.14258/jcprm.2019046466. (in Russ.).

Kalyuta Ye.V., Mal'tsev M.I., Markin V.I., Katrakov I.B., Bazarnova N.G. Khimiya rastitel'nogo syr'ya, 2016, no. 2, pp. 145–152. DOI: 10.14258/jcprm.2016021296. (in Russ.).

Kalyuta Ye.V., Mal'tsev M.I., Markin V.I., Mashkina Ye.I. Khimiya rastitel'nogo syr'ya, 2021, no. 2, pp. 361–368. DOI: 10.14258/jcprm.2021029732. (in Russ.).

Kalyuta E.V., Maltsev M.I., Markin V.I., Mashkina E.I. Russian Journal of Bioorganic Chemistry, 2022, vol. 48, no. 7, pp. 1416–1421. DOI: 10.1134/S1068162022070081

Kalyuta Ye.V., Mal'tsev M.I., Markin V.I., Katrakov I.B., Bazarnova N.G. Khimiya rastitel'nogo syr'ya, 2013, no. 3, pp. 249–253. DOI: 10.14258/jcprm.1303249. (in Russ.).

Krivoshapkin P.V., Krivoshapkina Ye.F., Nazarova Ye.A., Stalyugin V.V. Osnovy kolloidnoy khimii. Poverkhnostnyye yavleniya i dispersnyye sistemy [Fundamentals of colloidal chemistry. Surface phenomena and disperse systems]. St. Pe-tersburg, 2019, 138 p. (in Russ.).

Praktikum po khimii i fizike polimerov. [Practical training in the chemistry and physics of polymers]. Ed. V.F. Kurenkov, Moscow, 1990, 304 p. (in Russ.).

Shramm G. Osnovy prakticheskoy reologii i reometrii. [Fundamentals of practical rheology and rheometry]. Ed. V.G. Kulichikhin, Moscow, 2003, 312 p. (in Russ.).

Pukhnachev V.V., Frolovskaya O.A., Petrova A.G. Izvestiya vysshikh uchebnykh zavedeniy. Severo-Kavkazskiy region. Seriya: Yestestvennyye nauki, 2020, no. 2, pp. 84-93. DOI: 10.18522/1026-2237-2020-2-84-93. EDN: KJNJFV. (in Russ.).

Kokoyeva A.A., Begiyeva M.B., Malkanduyev YU.A., Dokshukina M.A. Fiziko-khimicheskiye aspekty izucheniya klas-terov, nanostruktur i nanomaterialov, 2019, no. 11, pp. 177–183. DOI: 10.26456/pcascnn/2019.11.177. (in Russ.).

Mal'tsev M.I., Kalyuta Ye.V., Bazarnova N.G., Markin V.I. Vestnik Altayskogo gosudarstvennogo agrarnogo universi-teta, 2020, no. 12, pp. 39–45. (in Russ.).

Padohin V.A., Ganiev R.F., Kočkina N.E. Doklady Akademii nauk, 2007, vol. 416, no. 2, pp. 219–221. (in Russ.).

Fedoseyeva T.V., Kochkina N.Ye., Padokhin V.A. Izvestiya vysshikh uchebnykh zavedeniy. Seriya: Khimiya i khimich-eskaya tekhnologiya, 2008, vol. 51, no. 11, pp. 44–46. (in Russ.).

Turayev A.S., Shomurotov Sh.A., Mukhamedzhanova M.Yu., Khaytmetova S.B., Khodzhakova D.A. Khimiya ras-titel'nogo syr'ya, 2008, no. 4, pp. 35–40. (in Russ.).

Minakov D.V., Chaschilov D.V., Minakova A.A., Markin V.I. Khimiya rastitel'nogo syr'ya, 2023, no. 3, pp. 271–281. DOI: URL: 10.14258/jcprm.20230312963. (in Russ.).

Published
2024-10-02
How to Cite
1. Kalyuta E. V., Markin V. I., Maltsev M. I., Cheprasova M. Y. STUDYING THE PHYSICAL AND CHEMICAL PROPERTIES OF SOLUTIONS OF CARBOXYMETHYLATED PINE WOOD // chemistry of plant raw material, 2024. № 3. P. 119-128. URL: http://journal.asu.ru/cw/article/view/15458.
Section
Biopolymers of plants