INVESTIGATION OF MECHANICAL PROPERTIES, MORPHOLOGY, AND BIODEGRADABILITY OF COMPOSITIONS BASED ON POLYLACTIDE AND POLYSACCHARIDES
Abstract
The blends of polylactide with ethyl cellulose and chitosan are obtained in a Brabender mixer under conditions of high temperature shear deformations at different initials ratios of reagents. The investigation of physicomechanical properties of compositions has shown that systems have high rigidity. To improve the elasticity poly(ethylene glycol) (PEG) and high-molecular polyolefin polydecene are added into compositions. It has turned out that polydecene weakly affects the mechanical characteristics, while PEG leads to noticeable increase in elongation at break. Biodegradability of compositions obtained is investigated by weight loss of samples after holding in soil, tests on fungus resistance, and analysis of film morphology by scanning electron microscopy after holding in soil. It is found that introduction of third component (PEG) leads to increase in composition biodegradability.Downloads
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Роговина С.З., Алексанян К.В., Новиков Д.Д., Прут Э.В., Ребров А.В. Получение и исследование смесей полиэтилена с природными полисахаридами и их производными // Высокомолек. соед. А. 2009. Т. 51. № 5. С. 813-822.
Wang X., Zhuang Y., Dong L. Study of biodegradable polylactide/poly(butylene carbonate) blend // J. Appl. Polym. Sci. 2013. Vol. 127. P. 471-477.
Anderson K.S., Lim S.H., Hillmyer M.A. Toughening of polylactide by melt blending with linear low-density polyethylene // J. Appl. Polym. Sci. 2003. Vol. 89. P. 3757-3768.
Feng Y., Hu Y., Yin J., Zhao G., Jiang W. High-impact poly(lactic acid)/poly(ethylene octene) blends prepared by reactive blending // Polym. Eng. Sci. 2013. Vol. 53. P. 389-396.
Feng F., Ye L. Morphologies and mechanical properties of polylactide/thermoplastic polyurethane elastomer blends // J. Appl. Polym. Sci. 2011. Vol. 119. P. 2778-2783.
Bitinis N., Verdejo R., Cassagnau P., Lopez-Manchado M.A. Structure and properties of polylactide/natural rubber blends // Mater. Chem. Phys. 2011. Vol. 129. P. 823-831.
Xie F., Li Q.F., Gu B., Liu K., Shen G.X. In vitro and in vivo evaluation of a biodegradable chitosan-PLA composite peripheral nerve guide conduit material // Microsurgery. 2008. Vol. 27. P. 471-479.
Li L., Ding S., Zhou C. Preparation and degradation of PLA/chitosan composite materials // J. Appl. Polym. Sci. 2004. Vol. 91. P. 274-277.
Nanda R., Sasmal A., Nayak P.L. Preparation and characterization of chitosan-polylactide composites blended with Cloisite 30B for control release of the anticancer drug paclitaxel // Carbohydr. Polym. 2011. Vol. 83. P. 988-994.
Suyatma N.E., Copinet A., Tighzert L., Coma V. Mechanical and barrier properties of biodegradable films made from chitosan and poly (lactic acid) blends // J. Polym. Environ. 2004. Vol. 12, N1. P. 1-6.
Baiardo M., Frisoni G., Scandola M., Rimelen M., Lips D., Ruffieux K., Wintermantel E. Thermal and mechanical properties of plasticized poly(L-lactic acid) // J. Appl. Polym. Sci. 2003. Vol. 90. P. 1731-1738.
Chieng B.W., Ibrahim N.A., Yunus W.M.Z.W., Hussein M.Z. Plasticized poly(lactic acid) with low molecular weight poly(ethylene glycol): mechanical, thermal, and morphology properties // J. Appl. Polym. Sci. 2013. Vol. 130. P. 4576-4580.
Cuenoud M., Bourban P.-E., Plummer C.J.G., Manson J.-A.E. Plasticization of poly-L-lactide for tissue engineering // J. Appl. Polym. Sci. 2011. Vol. 121. P. 2078-2088.
Gumus S., Ozkoc G., Aytac A. Plasticized and unplasticized PLA/organoclay nanocomposites: short- and long-term thermal properties, morphology, and nonisothermal crystallization behavior // J. Appl. Polym. Sci. 2012. Vol. 123. P. 2837-2848.
Sungsanit K., Kao N., Bhattacharya S.N. Properties of linear poly(lactic acid)/polyethylene glycol blends // Polym. Eng. Sci. 2012. Vol. 52. P. 108-116.
Hu Y., Hu Y.S., Topolkaraev V., Hiltner A., Baer E. Crystallization and phase separation in blends of high stereoregular poly(lactide) with poly(ethylene glycol) // Polymer. 2003. Vol. 44. P. 5681-5689.
Piorkowska E., Kulinski Z., Galeski A., Masirek R. Plasticization of semicrystalline poly(L-lactide) with poly(propylene glycol) // Polymer. 2006. Vol. 47. P. 7178-7188.
Pluta M. Morphology and properties of polylactide modified by thermal treatment, filling with layered silicates and plasticization // Polymer. 2004. Vol. 45. P. 8239-8251.
Gupta A.P., Kumar V. New emerging trends in synthetic biodegradable polymers – polylactide: a critique // Eur. Polym. J. 2007. Vol. 43. P. 4053-4074.
Wu C.-S. Polylactide-based renewable composites from natural products residues by encapsulated film bag: characterization and biodegradability // Carbohydr. Polym. 2012. Vol. 90. P. 583-591.
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