X-RAY STRUCTURAL ANALYSIS OF COTTONS AND HERBACEOUS CELLULOSE

UDC 661.728

  • Kseniya Sergeyevna Momziakova Kazan National Research Technological University Email: ksunya-fadeeva@yandex.ru
  • Aleksey Aleksandrovich Shinkarev Kazan National Research Technological University Email: shinkarev84@mail.ru
  • Timur Rustamovich Deberdeev Kazan National Research Technological University Email: deberdeev@mail.ru
  • Zimfira Talgatovna Valishina Kazan National Research Technological University Email: zimval1@yandex.ru
  • Aleksandr Aleksandrovich Berlin Federal Research Center of Chemical Physics named after N.N. Semyonov RAS Email: berlin@chph.ras.ru
  • Rustam Yakubovich Deberdeev Kazan National Research Technological University Email: rudeberdeev@mail.ru
Keywords: cellulose powder, microcrystalline cellulose, nanocellulose, cotton, flax, alfalfa, oats, X-ray structural analysis, FTIR spectroscopy, structural parameters, extruder

Abstract

It was found that the extrusion treatment of cotton cellulose in an aqueous medium, followed by drying and grinding on a hammer mill leads to a decrease in the crystallite size in the transverse direction ([110] and [100]) as a result of mechanical destruction of cellulose macromolecules, and the subsequent acid hydrolysis of cellulose in H2SO4 solutions to an increase in the size of crystallites in the transverse direction ([110], [110] and [100]) due to co-crystallization processes. It is shown that alkaline cooking of cellulose-containing material, followed by extrusion processing, washing, drying and grinding on a hammer mill leads to an increase in the transverse dimensions of crystallites in the [110] and [100] directions for flax cellulose and in the [110], [110] and [100] – for cellulose from oats and alfalfa as a result of partial removal of lignin and hemicelluloses from the cellulose-containing material.

Differences were revealed in the sizes of the coherent scattering regions and the parameters of the crystallographic cell of cellulose samples from cotton and herbaceous plants (flax, oats, and alfalfa), as well as between samples from oats and alfalfa obtained under the same conditions with the same type of feedstock (straw).

It has been established that the proposed stepwise technology for processing cotton and linen fibers leads to a slight decrease in the degree of crystallinity and the average degree of polymerization, which indicates that the developed technology for obtaining high-viscosity powder celluloses for various purposes is promising.

Correlation coefficients are established between the values of the degree of ordering of the structure of cellulose samples from various plant raw materials, calculated using X-ray diffraction analysis and FT-IR spectroscopy, which make it possible to adequately compare all the known literature and experimental data.

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Author Biographies

Kseniya Sergeyevna Momziakova, Kazan National Research Technological University

аспирант

Aleksey Aleksandrovich Shinkarev, Kazan National Research Technological University

кандидат геолого-минералогических наук, доцент

Timur Rustamovich Deberdeev, Kazan National Research Technological University

доктор технических наук, профессор, заведующий кафедрой

Zimfira Talgatovna Valishina, Kazan National Research Technological University

доктор химических наук, профессор

Aleksandr Aleksandrovich Berlin, Federal Research Center of Chemical Physics named after N.N. Semyonov RAS

доктор химических наук, профессор, академик РАН, заведующий кафедрой химической физики

Rustam Yakubovich Deberdeev, Kazan National Research Technological University

доктор технических наук, профессор, главный научный сотрудник

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Published
2021-09-27
How to Cite
1. Momziakova K. S., Shinkarev A. A., Deberdeev T. R., Valishina Z. T., Berlin A. A., Deberdeev R. Y. X-RAY STRUCTURAL ANALYSIS OF COTTONS AND HERBACEOUS CELLULOSE // chemistry of plant raw material, 2021. № 3. P. 61-71. URL: http://journal.asu.ru/cw/article/view/8852.
Section
Biopolymers of plants