STUDY OF TECHNICAL CELLULOSE AS A MATRIX-SORBENT TO DEVELOP EXPRESS ANALYTIC SYSTEM FOR WATER SAFETY CONTROL

UDC 676.164.8 544.723.2:547.556.9

  • Tatiana Maslakovа Ural State Forestry University Email: maslakovati@gmail.com
  • Alesya Vurasko Ural State Forestry University Email: vurasko2010@yandex.ru
  • Inna Pervova Ural State Forestry University Email: biosphera@usfeu.ru
  • Pavel Maslakov Ural State Forestry University Email: pashalx@gmail.com
  • Ludmila Aleshina Ural State Economic University Email: alv@usue.ru
  • Irina Shapovalova Ural State Forestry University Email: art-istsky@yandex.ru
Keywords: rice husk, oat straw, cellulose matrix composition, modified sorbents, water safety control, hetarylformazans, solid-phase reactive indicator system, mercury, test-systems, express analytic system

Abstract

The study presented by the authors is devoted to the study of the properties and the possibility of using technical cellulose from non-wood plant raw materials as a solid-phase matrix to obtain solid-phase reactive indicator systems by the following methods: synthesis method on the base of a hetarylformazane immobilized on a cellulose matrix and development of analytical systems based on preconcentration of the determined metal ion by a matrix with subsequent its «revealing» by the formazan («revealing» method).

The article focuses on determination of optimal combinations of chromogenic organic reagents (hetarylformazanes) and cellulose-based matrices for developing solid-phase reaction-based indicator systems. Adsorption features of formazan reagents onto cellulose matrices was studied. It has been established the relation between the reagent molecule structure, composition of cellulose matrix and analytical properties of the test-systems synthesized to determine metal ions. Different approaches were developed and applied to reveal the visually observable and easily measured effect due to cellulose properties as well as properties of hetarylformazanes fixed on the surface of the matrix. This fact allows to control sensitivity and selectivity of solid-phase reactive indicator systems for water quality assessment.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

Author Biographies

Tatiana Maslakovа, Ural State Forestry University

PhD (Сhemical),  Associate professor of the Department of physical and chemical technologies in environmental engineering

Alesya Vurasko, Ural State Forestry University

DSc (Technical), Professor, Head of the Department technology of pulp and paper industries and polymer processing

Inna Pervova, Ural State Forestry University

DSc (Chemical), Professor of the Department of physical and chemical technologies in environmental engineering

Pavel Maslakov, Ural State Forestry University

Assistant of the Department of physical and chemical technologies in environmental engineering

Ludmila Aleshina, Ural State Economic University

Associate professor of the Department of physics and chemistry

Irina Shapovalova, Ural State Forestry University

applicant

References

Materialy iz netraditsionnykh vidov volokon: tekhnologii polucheniya, svoystva, perspektivy primeneniya [Materials from non-traditional types of fibers: production technologies, properties, application prospects], ed. A.V. Vurasko. Yekaterinburg, 2020, 252 p. (in Russ.).

Simonova Ye.I. Polucheniye i svoystva sorbtsionnykh materialov na osnove tekhnicheskoy tsellyulozy iz nedrevesnogo rastitel'nogo syr'ya: diss. … kand. tekhn. nauk. [Obtaining and properties of sorption materials based on technical cel-lulose from non-woody plant raw materials: diss. ... Cand. tech. sciences]. Yekaterinburg, 2018, 167 p. (in Russ.).

Meena P.L., Saxena R., Sharma N. International Journal of Agriculture and Food Science Technology, 2014, vol. 5, no. 4, pp. 287–296.

Etorki A.M., Shaban I.S. American Journal of Environmental Protection, 2015, vol. 4, no. 2, pp. 105–109. DOI: 10.11648/J.AJEP.20150402.16.

Repo E., Warchoł J.K., Sillanpää M. Journal of Sustainable Development of Energy. Water and Environment Systems, 2017, vol 5, no. 1, pp. 89–100. DOI: 10.13044/j.sdewes.d5.0135.

Castro G.R., Cristante V.M., Padilha C.C.F., Jorge S.M.A., Florentino A.O., Prado A.G.S., Padilha P.M. Micro-chimica Acta, 2008, vol. 160, pp. 203–209. DOI:10.2478/v10026-010-0002-5.

Castro R.S.D., Caetano L., Ferreira G., Padilha P.M., Saeki M.J., Zara L.F., Martines M.A.U., Castro G.R. Industrial and Engineering Chemistry Research, 2011, vol. 50, pp. 3446–3451. DOI:10.1021/ie101499e.

Yan L., Wang Y., Chen J. Journal of Applied Polymer Science, 2008, vol. 110, no. 3, pp. 1330–1335. DOI:10.1002/app.28562.

Łukaszczyk J., Łȩkawska E., Lunkwitz K., Petzold G. Journal of Applied Polymer Science, 2004, vol. 92, no. 3, pp. 1510–1515. DOI:10.1002/app.20082.

Progress v khimii formazanov [Progress in the chemistry of formazans], ed. I.N. Lipunov, G.I. Sigeykin. Moscow, 2009, 296 p. (in Russ.).

Pervova I.G., Skorykh T.V., Maslakova T.I., Mel’nik T.A., Lipunova G.N., Lipunov I.N., Wang Li, Chen Chen. Journal of Shenyang University of Chemical Technology, 2011, no. 2, pp. 183–191. DOI: 10.1134/S1070363218120423.

Şenöz H. Hacettepe Journal of Biology and Chemistry, 2012, vol. 40, no. 3, pp. 293–301.

Vurasko A.V., Simonova E.I., Glukhikh V.V., Minakova A.R. CEUR workshop proceedings Сер. "CSASE 2018 - Proceedings of the Annual Scientific International Conference on Computer Systems, Applications and Software Engi-neering" 2018. 2018 Annual scientific international conference on computer systems, applications and software engi-neering, CSASE 2018. Nizhniy Tagil, 2018, pp. 7–16.

Shapovalova I., Vurasko A., Petrov L., Kraus E., Heinrich L., Michael H., Stoyanov O. Journal of Applied Polymer Science, 2018, vol. 135, no. 5, 45796. DOI: 10.1002/app.45796.

Vurasko A.V., Simonova Ye.I., Minakova A.R. Izvestiya Sankt-Peterburgskoy lesotekhnicheskoy akademii, 2019, no. 226, pp. 139–154. DOI: 10.21266/2079-4304.2019.226.139-154. (in Russ.).

GOST 7690-76. Tsellyuloza, bumaga i karton. Metod opredeleniya belizny [GOST 7690-76. Pulp paper and board. Method of determination of brightness]. Moscow, 1999, 7 p. (in Russ.).

Uchiumi A., Takatsu A., Tanaka H. Analytical sciences, 1991, vol. 7, pp. 459–462.

Buzykin B.I., Lipunova G.N., Sysoyeva L.P., Rusinova L.I. Khimiya formazanov. [Chemistry of formazans]. Moscow, 1992, 376 p. (in Russ.).

Chemical Pulping Part 1, Fibre Chemistry and Technology/ Paper Engineers’ Association / Paperi ja Puu Oy, Helsin-ki, 2011, 748 р.

Fengel D., Wegener G. Wood-Chemistry, ultrastructure, reactions. Walter de Gruyter, Berlin, Germany, 1989, 613 p.

Liu S., Tao D., Bai H., Liu X. Journal of Applied Polymer Science, 2012, vol. 126, pp. E281–E289. DOI: 10.1002/app.36637.

Maslakova T.I., Pervova I.G., Zhelnovach A.V., Maslakov P.A., Simonova Ye.I., Vurasko A.V. Sorbtsionnyye i khromatograficheskiye protsessy, 2017, vol. 17, no. 3, pp. 398–406. (in Russ.).

Al-Araji Y.H., Shneine J.K., Ahmed A.A. International Journal of Research in Pharmacy and Chemistry, 2015, vol. 5, no. 1, pp. 41–76.

Maslakova T.I., Pervova I.G., Maslakov P.A., Simonova Ye.I., Vurasko A.V. Sorbtsionnyye i khromatograficheskiye protsessy, 2016, vol. 16, no. 6, pp. 847–857. (in Russ.).

Jensen F. Introduction to Computational Chemistry, Third Edition, Wiley, 2017, 661 p.

Ramos-Morales F.R., Durand-Niconoff S., Correa-Basurto J., Meléndez-Bustamante F.J., Cruz-Sánchez J.S. The Journal of the Mexican Chemical Society, 2008, vol. 52, no. 4, pp. 241–248. DOI: 10.1007/s12039-011-0119-y.

Jamshaid A., Hamid A., Muhammad N., Naseer A., Ghauri M., Iqbal J., Rafiq S., Shah N.S. ChemBioEng Reviews, 2017, no. 4, pp. 1–18. DOI: 10.1002/cben.201700002.

Madivoli E.S., Kareru P.G., Gachanja A.N., Mugo S., Murigi M.K., Kairigo P.K., Kipyegon C., Mutembei J.K., Njonge F.K. International Research Journal of Pure & Applied Chemistry, 2016, vol. 12, no. 3, pp. 1–9. DOI: 10.9734/IRJPAC/2016/28548.

Wang Z., Hauser P.J., Rojas O.J. Journal of Research, 2015, vol. 2, no. 2, pp. 13–19. DOI: 10.14504/ajr.2.2.2.

Published
2021-12-14
How to Cite
1. MaslakovаT., Vurasko A., Pervova I., Maslakov P., Aleshina L., Shapovalova I. STUDY OF TECHNICAL CELLULOSE AS A MATRIX-SORBENT TO DEVELOP EXPRESS ANALYTIC SYSTEM FOR WATER SAFETY CONTROL // chemistry of plant raw material, 2021. № 4. P. 351-359. URL: http://journal.asu.ru/cw/article/view/9485.
Section
Technology