Investigating of cardanol composition with two dimensional full gas chromatography with time of flight mass-spectrometry technique (GCxGC-TOF MS)

  • Олег Федорович Шишлов Uralchimplast Ltd., Severnoe shosse, 21, Nizhny Tagil, Sverdlovsk region, 622012 Email: o.shishlov@ucp.ru
  • Jitka Zrostlíková LECO European Technical Centre Prague, Sokolovská, 219, 190 00, Prague, 9 Email: jitka.zrostlikova@leco.cz
  • Дмитрий Борисович Чиркин LECO Ural branch, ul. Bebelia,17, Yekaterinburg, Sverdlovsk Region, 620034 Email: chirkin@leco.ru
Keywords: cardanol, chromatography, mass-spectrometry, cardol, composition

Abstract

With the use of GCxGC-TOF MS technique qualitative and quantitative composition of a complicated material – cardanol was investigated. The presence of 33 substances belonging to 4 structural groups was established. Main constituents of cardanol produced by Southern Agro Phenols Limited (SAPL), Tamil Nadu state, India were found to be: 3-pentadecylphenol – 33,4%, 3-pentadecadienylphenol – 24,4%, 3-pentadecatrienylphenol – 33,5%. GC´GC method possess a brand new possibility on dividing  components, which is very useful for isolating of individual substances varying in number of double bonds in side chains.

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Author Biographies

Олег Федорович Шишлов, Uralchimplast Ltd., Severnoe shosse, 21, Nizhny Tagil, Sverdlovsk region, 622012
директор по науке и развитию, кандидат технических наук, тел.: (3435) 34-65-92, факс: (3435) 34-69-85
Jitka Zrostlíková, LECO European Technical Centre Prague, Sokolovská, 219, 190 00, Prague, 9
TOF MS специалист, Ph. D.
Дмитрий Борисович Чиркин, LECO Ural branch, ul. Bebelia,17, Yekaterinburg, Sverdlovsk Region, 620034
директор, тел./факс: (343) 373-74-79

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Published
2013-10-20
How to Cite
1. Шишлов О. Ф., Zrostlíková J., Чиркин Д. Б. Investigating of cardanol composition with two dimensional full gas chromatography with time of flight mass-spectrometry technique (GCxGC-TOF MS) // chemistry of plant raw material, 2013. № 3. P. 161-167. URL: http://journal.asu.ru/cw/article/view/jcprm.1303161.
Section
Low-molecular weight compounds