APPLICATION OF HEADSPACE ANALYSIS FOR ACQUISITION OF EUCALYPTUS VIMINALIS (EUCALYPTI VIMINALIS LABILL) «FINGERPTINT»
Abstract
The ratio of gas leaf extract component peak areas Eucalyptus (Eucalyptus viminalis Labill): α-pinene, camphene, β-pinene, α-fellandren, p-cymene, 1,8-cineol, 4-terpineol, α-terpineol and aromadendrene was taken for typical chromatographic spectrum. The evaluation of the accuracy of chromatographic spectra of leaves Eucalyptus obtained by Headspace-GC-MS and Headspace -SPME-GC-MS was carried out. For the first time it was invited to use the chromatographic spectra as the objective characteristics of the chemical identity of leaves Eucalyptus instead botanical identification methods. To evaluate the relationship between the results of samples processed by principal component analysis was used program «Statistica». The analysis of the sorption properties of the sorbents Tenax ™ TA, Carbopack In, Porapak Q, Haye Sep N, MN-202 with respect to volatile organic compounds (VOCs), eucalyptus leaves was carried out. It was provided to use sorption tubes based on injecting needles, filled selected polymeric sorbents Porapak Q, Haye Sep N, MN-202, on which the concentrated analytes as standard of composition volatile organic compounds (VOCs) Eucalyptus viminalis, including the identification of the raw material. The parameters of the sorption of VOCs and storage life of sorption tubes with analytes ware determined. It is recommended to use the chromatographic spectrum to create a database of chromatographic spectra characteristic of plant raw materials.Downloads
References
Золотов Ю.А. О некоторых тенденциях развития аналитической химии // Заводская лаборатория. Диагностика материалов. 2012. Т. 78, №9. С. 5.
Виттенберг А.Г., Иоффе Б.В. Газовая экстракция в хроматографическом анализе: парофазный анализ и родственные методы. Л., 1982. 280 с.
Nikam P.H., Kareparamban J., Jadhav A., Kadam V. Future Trends in Standardization of Herbal Drugs // Journal of Applied Pharmaceutical Science. 2012. Vol. 2 (6). Pp. 38–44.
Guidance for Industry Botanical Drug Products. U.S. Department of Health and Human Services Food and Drug Ad-ministration. Center for Drug Evaluation and Research (CDER) 2004. 48 p.
Вигдергауз М.С., Семенченко Л.В., Езрец В.А., Богословский Ю.Н. Качественный газохроматографический анализ. М., 1978. 44 с.
Патент №2341792 (РФ). Фингерпринтинг сложных смесей, содержащих углеводороды / Эйде Ингвар, Сулсен Колбьорн / 2008.
Фомина Н.В. Идентификация нефтей Самарской области по многомерному массиву данных : автореф. дис. … канд. хим. наук. Самара, 2014. 25 с.
Tistaert C., Dejaegher B., Vander Heyden Y. Chromatographic separation techniques and data handling methods for herbal fingerprints: A review // Analytica Chimica Acta. 2011. Vol. 690. Рp. 148–161.
Feng Gan, Runyi Ye. New approach on similarity analysis of chromatographic fingerprint of herbal medicine // Journal of Chromatography А. 2006. Vol. 1104. Рp. 100–105.
Latit Giri, Harish C Andola, Vijay Kant Purohit, Rawat M.S.M., Rawal R.S., Bhatt I.D. Chromatographic and spectral fingerprinting standartization of traditional medicines: an overview as modern tools // Research Journal of Phitochemistry. 2010. Vol. 4 (4). Pp. 234–241.
Tripathi I.P., Mahendra K.R., Pardhi Yogesh, Dwivedi Atul, Dwivedi Noopa, Kamal Arti, Gupta Priyanka. HPLC Analysis of methanolic extract of some medicinal plant leaves of Myrtaceae family. // International Pharmaceutica Sciencia. 2012. Vol. 2, N3. Pp. 49–53.
Alaerts G., Matthijs N., Smeyers-Verbeke J., Vander Heyden Y. Chromatographic fingerprint development for herbal extracts: a screening and optimization methodology on monolithic columns. // J Chromatogr A. 2007. Vol. 1172(1). Pp. 1–8.
Dejaegher B., Alaerts G., Matthijs N. Methodology to develop liquid chromatographic fingerprints for the quality control of herbal medicines // Acta Chromatographica. 2010. Vol. 22. N2. Pp. 237–258.
Se Mi Yu, Eun Kyung Kim, Je Hyun Lee, Kang Ro Lee, Hong J. Development of Fingerprints for Quality Control of Acorus species by Gas Chromatography/Mass Spectrometry // Bull. Korean Chem. Soc. 2011. Vol. 32. N5. Pp. 1547–1553.
Siu-Kay Wong, Shu-Ki Tsui, Sik-Yiu Kwan, Xiao-Li Su, Rui-Chao Lin, Li-Ming Tang, Jian-Xing Chen. Establishment of Characteristic Fingerprint Chromatogram for the Identification of Chinese Herbal Medicines // Journal of Food and Drug Analysis. 2004. Vol. 12. N2. Pp. 110–114.
Rzepa J., Sajewicz M., Baj T., Gorcyca P., Wlodarek M., Glowniak K., Hajnos M. W., Kowaslska T. A Comparison of Methodical Approaches to Fingerprinting of the Volatile Fraction from Winter Savory (Satureja Montana) // Chromatography Research Internetional. 2012. Vol. 2012. Р. 8.
Daszykowski M., Sajewicz M., Rzepa J., Hajnos M., Staszek D., Wojtal Ł., Kowalska T., Waksmundzka-Hajnos M., Walczak B. Comparative Analysis of the Chromatographic Fingerprints of Twenty Different Sage (Salvia L.) Species // Acta Chromatographica 2009. Vol. 21. N4. Pp. 513–530.
Онучак Л.А., Арутюнов Ю.И., Куркин В.А., Платонов И.А., Никитченко Н.В. Газохроматографические характеристики летучих веществ в плодах и препаратах расторопши пятнистой (Silybumm arianum L.) // Журнал аналитической химии. 2012. Т. 67. №6. С. 619–624.
Vu D.-T., Nicholas P.E., Erikson C.M. Characterization of Volatiles Using Solid-Phase Microextraction // Gas Chro-matography-Mass Spectrometry (SPME/GC-MS). Two Customs Applications. U.S. Customs Serv. Lab. Bull. 2000. Vol. 10. Pp. 1–9.
Павлова Л.В., Платонов И.А., Новикова Е.А., Никитченко Н.В. Хромато-масс-спектрометрический анализ (Eucalypti viminalis Labill) с использованием различных способов пробоподготовки // Аналитика и контроль. 2013. Т. 17, №3. С. 304–313.
Макаров Е.В. Проточная твердофазная микроэкстракция как новый способ сорбционной пробоподготовки в газовой хроматографии : автореф. дис. … канд. хим. наук. СПб., 2004. 22 с.
Другов Ю.С., Родин А.А. Пробоподготовка в экологическом анализе. СПб., 2002. 755 с.
Пастухов А.В. Физико-химические свойства и структурная подвижность сверхсшитых полистиролов : автореф. дис. … докт. хим. наук. М., 2008. 52 с.
ГОСТ Р ИСО 16017-1-2007. Воздух атмосферный, рабочей зоны и замкнутых помещений. М., 2008. 41 с.
Фармакопея СССР. Изд. 11, вып. 2. М., 1989. 216 с.
Ботаника. Руководство к практическим занятиям : учебное пособие / под. ред. Е.И. Барабанова, С.Г. Зайчиковой. М., 2012. 304 с.
Siu-Kay Wong, Shu-Ki Tsui, Sik-Yiu Kwan, Xiao-Li Su, Rui-Chao Lin, Li-Ming Tang, Jian-Xing Chen. Establishment of characteristic fingerprint chromatogram for the identification of chinese herbal medicines // Journal of Food and Drug Analysis. 2004. Vol. 12. N2. P. 110.
Buenoa P.C.P., Juniorb M.G., Bastos J.K. GC-MS Fingerprinting of 12 Eucalyptus Species // Natural Product Com-munications 2014. Vol. 9. N12. Pp. 1781–1790.
Другов Ю.С., Родин А.А. Газохроматографический анализ природного газа : практическое руководство. М., 2009. 174 с.
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