FUNCTIONAL MATERIALS FROM PAPER WASTES. I. FROM WASTE NEWSPRINT PAPER AND CARDBOARD TO HIGH-GRADE CELLULOSE FIBERS
Abstract
Utilization of paper wastes as renewable resource of lignocellulosic constituents has the opportunity to promote a cleaner environment and to prepare valuable materials. This paper describes our study on an isolation of low-fiber powder cellulose from two grades of wastes as feedstocks: waste newsprint paper and cardboard wrapper through recycling including a thermal defibration, an alkali treatment with a solution of NaOH with a concentration from 0.03 to 1.00 М, a bleaching with a solution of Н2О2 with a concentration from 0.8 to 2.6 М followed with an acid hydrolysis of the pretreated species with a solution of HNO3 of 1.5 and 3.0 M. An impact of the pretreatment on sizes of fibers was evaluated with a stereoscopic microscopy. The powder celluloses obtained as a result of the acid hydrolysis exhibited the structure of cellulose I revealed with a WAXS method and were of a high-grade purity, according to EDXA. Sorption capacities of the powder celluloses from the waste cardboard and newsprint towards a dye methylene blue were 6.67 mg∙g-1 and 8.75 mg∙g-1 correspondingly.
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Abitbol T., Rivkin A., Cao Y., Nevo Y., Abraham E. et al. Current Opinion in Biotechnology, 2016, vol. 39, pp. 76–88.
Klemm D., Kramer F., Moritz S., Lindström T., Ankerfors M., et al. Angew. Chem. Int. Ed., 2011, vol. 50, pp. 5438–5466.
Kotelnikova N.E. Struktur und Reaktivitat der Cellulose: Thes. VII Internat. Arbeitseminar. Reinhardsbrunn, DDR, 1988. S. 91–110.
Petropavlovskii G.A., Kotel'nikova N.E., Vasil'eva V.V., Volkova V.A. Cellulose Chem. Тechnol., 1971, vol. 2, no. 5, pp. 105–116.
Ejikeme P.M. Cellulose, 2008, vol. 15, pp. 141–147.
Vurasko A.V., Ageev A.Ia., Ageev M.A. Tekhnologiia polucheniia, obrabotki i pererabotki bumagi i kartona. [Tech-nology of production, processing and processing of paper and paperboard]. Ekaterinburg, 2011, 272 p. (in Russ.).
Lim Y.H., Leng Chew I.M., Choong Th.Sh.Y., Tan M.C., Tan K.W. Nanocrystalline cellulose isolated from oil palm empty fruit bunch and its potential in cadmium metal removal. MATEC Web of Conferences 59, 04002. 2016. ICFST 2016.
Chen N., Zhu J.Y., Tong Z. Cellulose, 2016, vol. 23, pp. 2573–2583.
Uyigue L., Okwonna O.O. J. Emerging Trends Engin Applied Sci. (JETEAS), 2013, vol. 4(1), pp. 126–132.
Wan Hazman D., Zaiton A.M., Mohd Nazlan M.M., Sugeng T., Mohd Bakri B., Zainab R. Carbohydrate Polymers, 2015, no. 118, pp. 165.
Bel'kovich V.V., Mikhailidi A.M., Kotel'nikova N.E., Vlasova E.N. Vestnik Sankt-Peterburgskogo gosudarstvennogo universiteta tekhnologii i dizaina. Seriia 1. Estestvennye i tekhnicheskie nauki, 2017, no. 1, pp. 60–65. (in Russ.).
Iagodin V.I., Antonov V.N. Izuchenie khimicheskogo sostava drevesnoi zeleni: metodich. osnovy. [The study of the chemical composition of woody greens: the methodological basis]. Riga, 1983, pp. 33–38. (in Russ.).
Kaewprasit Ch., Hequet E., Abidi N., Gourlot J.P. J. Cotton Sci., 1998, vol. 2, pp. 164–173.
Gregg S.J., Sing K.S.W. Adsorption surface area and porosity. Academic Press, Inc., Ltd., London, 1967, 371 p.
Brovarova O.V. Poluchenie i issledovanie svoistv sorbtsionnykh materialov na osnove rastitel'nykh biopolimerov: dis. … kand. khim. nauk. [Reception and research of properties of sorption materials on the basis of plant biopolymers: the dissertation of Candidate of Chemical Sciences]. Syktyvkar, 2006, 157 p. (in Russ.).
Mikhailidi A.M., Kotel'nikova N.E., Gen'sh K.V., Kushnir E.Iu., Bazarnova N.G. Khimiia rastitel'nogo syr'ia, 2013, no. 1, pp. 15–28. (in Russ.).
Paria S., Manohar C., Khilar K.C. Colloid and Surfaces A: Physicochem. Engineering Aspects, 2005, vol. 252, iss. 2-3, pp. 221–229.
Kaliuta E.V. Molekuliarno-massovye kharakteristiki efirov tselliulozy, poluchennye pri karboksimetilirovanii i nitrovanii drevesiny: dis. … kand. khim. nauk. [Molecular-mass characteristics of cellulose esters obtained by carboxymethylation and nitration of wood: the dissertation of Candidate of Chemical Sciences]. Krasnoyarsk, 2007, 141 p. (in Russ.).
Kucic D., Miljanic S., Rozic M. The Holistic Approach to Environment, 2011, vol. 1, no. 2, pp. 39–49.
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