SYNTHESIS, STRUCTURE AND PROPERTIES OF ORGANIC GELS BASED ON LARCH BARK TANNINS AND HY-DROLYSIS LIGNIN

UDC 547.992.3

  • Nadezhda Mikhailovna Mikova Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center KSC SB RAS https://orcid.org/0000-0003-3360-9093 Email: nm@icct.ru
  • Elena Valentinovna Mazurova Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center KSC SB RAS Email: len.mazurova@yandex.ru
  • Ivan Petrovich Ivanov Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center KSC SB RAS https://orcid.org/0000-0001-6241-3474 Email: ivanov@icct.ru
  • Boris Nikolayevich Kuznetsov Институт химии и химической технологии СО РАН, ФИЦ Красноярский научный центр СО РАН Email: bnk@icct.ru
DOI_disc_logo https://doi.org/10.14258/jcprm.2021029635
Keywords: organic gels, preparation, larch bark tannins, hydrolysis lignin, structure, adsorption properties

Abstract

For the first time, tannin-lignin-formaldehyde and tannin-lignin-furfuryl organic gels were obtained on the basis of larch bark tannins and hydrolysis lignin by sol-gel condensation with formaldehyde and furfuryl alcohol. Their physico-chemical properties were studied by varying the content of lignin (from 5 to 30 wt%) and a fixed mass ratio of polyphenolic substances to the crosslinking reagent (1 : 1.5). With an increase in the lignin content the density of tannin-lignin formaldehyde gels decreases from 0.83 to 0.53 g/ cm3, and that of tannin-lignin-furfuryl gels is from 0.32 to 0.14 g / cm3. According to the FTIR data, the structures of tannin-lignin-formaldehyde and tannin-lignin-furfuryl gels are formed by aromatic fragments cross-linked with methylene and methylene-ether bridges. Scanning electron microscopy shows that the addition of appropriate amounts of lignin to tannins (up to 10 wt% when using formaldehyde and up to 20 wt% when using furfuryl alcohol) promotes the formation of gels with a more developed porous structure. In the case of tannin-lignin-formaldehyde gel, the specific surface area and sorption of methylene blue are 12 m2 / g and 43 mg / g and for tannin-lignin-furfuryl gel – 72 m2 / g and 114.5 mg/g, respectively. It was found that an increase in the lignin content in the gel composition over 20 wt.% is accompanied by the phase localization of lignin (precipitation), which reduces the strength of the resulting gel and reduces its specific surface area.

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Author Biographies

Nadezhda Mikhailovna Mikova, Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center KSC SB RAS

кандидат химических наук, старший научный сотрудник

Elena Valentinovna Mazurova , Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center KSC SB RAS

кандидат технических наук, старший научный сотрудник

Ivan Petrovich Ivanov, Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center KSC SB RAS

старший научный сотрудник, кандидат технических наук

Boris Nikolayevich Kuznetsov, Институт химии и химической технологии СО РАН, ФИЦ Красноярский научный центр СО РАН

доктор химических наук, профессор, руководитель научного направления ФИЦ Красноярский научный центр СО РАН, заведующий лабораторией

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Published
2021-06-10
How to Cite
1. Mikova N. M., Mazurova E. V., Ivanov I. P., Kuznetsov B. N. SYNTHESIS, STRUCTURE AND PROPERTIES OF ORGANIC GELS BASED ON LARCH BARK TANNINS AND HY-DROLYSIS LIGNIN // chemistry of plant raw material, 2021. № 2. P. 109-122. URL: http://journal.asu.ru/cw/article/view/9635.
Issue
No 2 (2021)
Section
Biopolymers of plants

Copyright (c) 2021 chemistry of plant raw material

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