PEROXIDE PULPING PROPERTIES OF ANNUAL PLANTS. 2. THE DYNAMICS OF TRANSFORMATION OF POLYSACCHARIDES IN THE DELIGNIFICATION OF WHEAT STRAW
Abstract
The dynamics dissolution of wheat straw polysaccharides during the oxygen delignification process was investigated with reaction mixture «H2O2 – H2O– АсОН – АсООН-catalyst». In the first period of peroxide pulping (until the release of solid residue 80–82%) mostly dissolve lignin and arabinoksilan. Further decline in output if you continue cooking comes at the expense of the dissolution products of oxidative and hydrolytic degradation of polysaccharides of solid residue.Downloads
Metrics
References
Вшивкова И.А., Пен Р.З., Каретникова Н.В. Свойства пероксидной целлюлозы из однолетних растений. 1. Кинетика делигнификации пшеничной соломы надуксусной кислотой // Химия растительного сырья. 2012. №4. С. 13–17.
Evtugin D.V., Deineko I.P., Neto P. Oxygen delignification in Aqueous Organic Solvents Media // Cellulose Chem. And Technology. 1999. Vol. 33. Pp. 103–123.
Сарканен К.В., Людвиг К.Х. Лигнины: пер. с англ. М., 1975. 631 с.
Латош М.В., Алексеев А.Д., Резников В.М. Механизм процесса окисления древесины и ее компонентов пере-кисью водорода. 3. Превращения перекиси водорода при окислении древесины в кислой среде // Химия дре-весины. 1980. №5. С. 41–46.
Латош М.В., Семенюк Е.Н., Алексеев А.Д., Резников В.М. Механизм процесса окисления древесины и ее компонентов перекисью водорода. 4. Деструкция целлюлозы при окислении перекисью водорода // Химия древесины. 1980. №5. С. 47–52.
Азаров В.И., Буров А.В., Оболенская А.В. Химия древесины и синтетических полимеров. СПб, 1991. 628 с.
Денситометр Сорбфил. Руководство пользователя. Краснодар, 2006. 17 с.
Dubois М., Gilles К.А., Hamilton J.К., Rebers Р.А., Smith F. Colorimetric Method for Determination of Sugars and Related Substances // Anal. Chem. 1956. Vol. 28. Рp. 350–355.
Оболенская А.В., Ельницкая З.П., Леонович А.А. Лабораторные работы по химии древесины и целлюлозы. М., 1991. 320 с.
Albersheim P. The primary cell wall // Plant biochemistry. Ed. J. Bonner, J.E. Varner. New-York, 1976. Pp. 225–274.
This work is licensed under a Creative Commons Attribution 4.0 International License.
The authors, which are published in this journal, agree to the following conditions:
1. Authors retain the copyright to the work and transfer to the journal the right of the first publication along with the work, at the same time licensing it under the terms of the Creative Commons Attribution License, which allows others to distribute this work with the obligatory indication of the authorship of this work and a link to the original publication in this journal .
2. The authors retain the right to enter into separate, additional contractual agreements for the non-exclusive distribution of the version of the work published by this journal (for example, to place it in the university depository or to publish it in a book), with reference to the original publication in this journal.
3. Authors are allowed to post their work on the Internet (for example, in a university repository or on their personal website) before and during the review process of this journal, as this may lead to a productive discussion, as well as more links to this published work.