APPLICATION OF IR ATR SPECTROSCOPY TO ASSESS THE DEGREE OF FIBER ORIENTATION IN THE ANISOTROPIC STRUCTURE OF PAPER
UDC 676.017.272
Abstract
The possibility of using IR ATR spectroscopy as a non-destructive method for monitoring the structure and physical and mechanical properties of paper has been demonstrated. Using non-destructive ultrasonic, spectroscopic, and destructive mechanical methods, comparative data were obtained on the degree of anisotropy of the paper structure, calculated through the ratio of characteristics in the machine and transverse directions (MD/CD). The experiment used laboratory anisotropic paper samples obtained by a dynamic sheet former; the degree of anisotropy according to TSIMD/CD ranged from 2.4 to 3.9. A close relationship has been proven between the amplitude coefficient A of the harmonics, which describe the dependence of D933/D489, on the angle of rotation of the sample relative to the optical axis of the spectrometer, and the characteristics of the degree of anisotropy measured by traditional methods. It has been established that all methods show a unidirectional change in the degree of anisotropy, but its relative value depends on the method and type of characteristic. The obtained dependences make it possible to predict the degree of paper anisotropy in terms of elastic and strength properties based on the results of processing the IR spectra of the samples. The use of the IR method may be relevant in cases where the sample size is limited, and it is possible to use only a non-destructive method for research.
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