FRACTIONATION OF PINE BARK TO OBTAIN AN ANTHOCYANIDINS AND POWDERED CELLULOSE

UDC 676.1.022.6.001.5; 676.014

  • Anna Ilyinichna Chudina Institute of Chemistry and Chemical Technology SB RAS FRC "Krasnoyarsk Scientific Center SB RAS" Email: bai77@list.ru
  • Irina Gennadyevna Sudakova Institute of Chemistry and Chemical Technology SB RAS FRC "Krasnoyarsk Scientific Center SB RAS" Email: sudakova_irina@mail.ru
  • Sergey Aleksandrovich Vorobyov Institute of Chemistry and Chemical Technology SB RAS FRC "Krasnoyarsk Scientific Center SB RAS" Email: yekspatz@yandex.ru
  • Boris Nikolaevich Kuznetsov Institute of Chemistry and Chemical Technology SB RAS FRC "Krasnoyarsk Scientific Center SB RAS", Siberian Federal University Email: bnk@icct.ru
DOI_disc_logo https://doi.org/10.14258/jcprm.20250418038
Keywords: pine bark, fractionation, peroxide catalytic delignification, anthocyanidins, powdered cellulose

Abstract

A new method for fractionating pine bark to obtain anthocyanidins and powdered cellulose was proposed. Anthocyanidins were isolated from pine bark by treatment with a solution of hydrochloric acid in ethanol with a yield of 10.1 wt.%. The presence of cyanidin and delphinidin in the composition of anthocyanidins was confirmed by UV spectroscopy method. Experimental and mathematical optimization of the process of peroxide catalytic delignification of pine bark after anthocyanidin extraction was carried out. Delignification process was carried out in the presence of MnSO4 catalyst at a hydromodulus of 20, a temperature of 100 °C and a duration of 4 hours. Using the method of mathematical optimization of the delignification process, optimal conditions for obtaining powdered cellulose from pine bark were established: the concentration of H2O2 6.4 wt.% and CH3COOH 57.1 wt.%. The experimental yield of cellulose product under optimal conditions was 34.1 wt.%, and the content of lignin in it was 1.1 wt.%, cellulose 86.4 wt.%. The crystallinity index of cellulose product was 0.81, the average particle size was 2.74 μm. The characteristics of powdered cellulose were determined by elemental and chemical analysis, FTIR, XRD, SEM, EDS and laser diffraction methods.

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Author Biographies

Anna Ilyinichna Chudina, Institute of Chemistry and Chemical Technology SB RAS FRC "Krasnoyarsk Scientific Center SB RAS"

Candidate of Chemical Sciences, Senior Researcher

Irina Gennadyevna Sudakova, Institute of Chemistry and Chemical Technology SB RAS FRC "Krasnoyarsk Scientific Center SB RAS"

Candidate of Technical Sciences, Senior Researcher

Sergey Aleksandrovich Vorobyov, Institute of Chemistry and Chemical Technology SB RAS FRC "Krasnoyarsk Scientific Center SB RAS"

Candidate of Chemical Sciences, Senior Researcher

Boris Nikolaevich Kuznetsov, Institute of Chemistry and Chemical Technology SB RAS FRC "Krasnoyarsk Scientific Center SB RAS", Siberian Federal University

Doctor of Chemical Sciences, Professor, Head of Research, Professor of the Department of Organic and Analytical Chemistry

References

Feng S., Cheng S., Yuan Z., Leitch M., Xu C. Renewable and Sustainable Energy Reviews, 2013, vol. 26, pp. 560–578. https://doi.org/10.1016/j.rser.2013.06.024.

Porter L.J., Hrstich L.N., Chan B.G. Phytochemistry, 1985, vol. 25(1), pp. 223–230. https://doi.org/10.1016/S0031-9422(00)94533-3.

Gao N., Cui H., Lang Y., Zhang W., Shu C., Wang Y., Bian Y., Li D., Li B. Food Research International, 2022, vol. 158, 111456. https://doi.org/10.1016/j.foodres.2022.111456.

Levdanskiy V.A., Butylkina A.I., Kuznetsov B.N. Khimiya rastitel'nogo syr'ya, 2006, no. 4, pp. 17–20. (in Russ.).

Khoo H.E., Azlan A., Tang S.T., Lim S.M. Food and Nutrition Research, 2017, vol. 61, 1361779. https://doi.org/10.1080/16546628.2017.1361779.

Posadino A.M., Giordo R., Ramli I., Zayed H., Nasrallah G.K., Wehbe Z., Eid A.H., Gürer E.S., Kennedy J.F., Al-dahish A.A., Calina D., Razis A.F.A., Modu B., Habtemariam S., Sharifi-Rad J., Pintus G., Cho W.C. Biomedicine and Pharmacotherapy, 2023, vol. 163, 114783. https://doi.org/10.1016/j.biopha.2023.114783.

Hossain S., Jalil A.M., Islam T., Rahman Md M. Heliyon, 2022, vol. 8, no. 11, e11667. https://doi.org/10.1016/j.heliyon.2022.e11667.

Liku E.T., Desissa T.D., Huluka A.W. Carbohydrate Polymer Technologies and Applications, 2024, vol. 8, 100626. https://doi.org/10.1016/j.carpta.2024.100626.

Taflick T., Schwendler L.A., Rosa S.M.L., Bica C.I.D., Nachtigall S.M.B. International Journal of Biological Macro-molecules, 2017, vol. 101, pp. 553–561. https://doi.org/10.1016/j.ijbiomac.2017.03.076.

Rietzler B., Ek M. ACS Sustainable Chemistry and Engineering, 2021, vol. 9 (3), pp. 1398–1405. https://doi.org/10.1021/acssuschemeng.0c08429.

Supriyadi D., Bodner S., Keckes J., Gindl-Altmutter W., Veigel S. Carbohydrate Polymer Technologies and Applica-tions, 2024, vol. 7, 100527. https://doi.org/10.1016/j.carpta.2024.100527.

Nair S.S., Yan N. Carbohydrate Polymers, 2015, vol. 134, pp. 258–266. https://doi.org/10.1016/j.carbpol.2015.07.080.

Kuznetsov B.N., Sudakova I.G., Garyntseva N.V., Tarabanko V.E., Chesnokov N.V., Djakovitch L., Pinel C. Topics in Catalysis, 2020, vol. 63, pр. 229–242. https://doi.org/10.1007/s11244-020-01244-9.

Patent 2400357C2 (RU). 2010. (in Russ.).

Patent 2400511C2 (RU). 2010. (in Russ.).

Patent 2332438C1 (RU). 2008. (in Russ.).

Toptunov Ye.A., Sevast'yanova Yu.V. Khimiya rastitel'nogo syr'ya, 2021, no. 4, pp. 31–45. https://doi.org/10.14258/jcprm.2021049186. (in Russ.).

Levdanskiy V.A., Polezhayeva N.I., Makiyevskaya A.I., Kuznetsov B.N. Khimiya v interesakh ustoychivogo razvitiya, 2000, vol. 8, no. 6, pp. 823–827. (in Russ.).

Obolenskaya A.V., Yel'nitskaya Z.P., Leonovich A.A. Laboratornyye raboty po khimii drevesiny i tsellyulozy: uchebnoye posobiye dlya vuzov. [Laboratory work on the chemistry of wood and cellulose: a textbook for universities]. Moscow, 1991, 320 p. (in Russ.).

Park S., Baker J.O., Himmel M.E. Parilla P.A., Jonson D.K. Biotechnology for Biofuels, 2010, vol. 3, 10. https://doi.org/10.1186/1754-6834-3-10.

Valentín L., Kluczek-Turpeinen B., Willför S., Hemming J., Hatakka A., Steffen K., Tuomela M. Bioresource Tech-nology, 2010, vol. 101, no. 7, pp. 2203–2209. https://doi.org/10.1016/j.biortech.2009.11.052.

Solár R., Melcer I., Kačík F. Cellulose. Chemistry and Technology, 1988, vol. 22, pp. 39–52.

Ku C.S., Mun S.P. Wood Science and Technology, 2007, vol. 41, no. 3, pp. 235–247. https://doi.org/10.1007/s00226-006-0103-8.

Diouf P.N., Tibirna C.M., García-Pérez M.-E., Royer M., Dubé P., Stevanovic T. Journal of Biomaterials and Nano-biotechnology, 2013, vol. 4, no. 3A, pp. 1–8. https://doi.org/10.4236/jbnb.2013.43A001.

Bahreini Z., Abedi M., Ashori A., Parach A. Heliyon, 2024, vol. 10, no. 11, e31795. https://doi.org/10.1016/j.heliyon.2024.e31795.

Sudakova I.G., Garyntseva N.V., Chudina A.I., Kuznetsov B.N. Kataliz v promyshlennosti, 2020, vol. 20, no. 1, pp. 67–75. https://doi.org/10.18412/1816-0387-2020-1-67-75. (in Russ.).

Pen R.Z. Planirovaniye eksperimenta v Statgraphics. [Experimental design in Statgraphics]. Krasnoyarsk, 2003, 246 p. (in Russ.).

Kuznetsov B.N., Chudina A.I., Kazachenko A.S., Fetisova O.Y., Borovkova V.S., Vorobyev S.A., Karacharov A.A., Gnidan E.V., Mazurova E.V., Skripnikov A.M., Taran O.P. Polymers, 2023, vol. 15, 2671. https://doi.org/10.3390/polym15122671.

Malyar Y.N., Sudakova I.G., Borovkova V.S., Chudina A.I., Mazurova E.V., Vorobyev S.A., Fetisova O.Y., El-sufiev E.V., Ivanov I.P. Polymers, 2023, vol. 1, 904. https://doi.org/10.3390/polym15040904.

Ditzel F.I., Prestes E., Carvalho B.M., Demiate I.M., Pinheiro L.A. Carbohydrate Polymers, 2017, vol. 157, pp. 1577–1585. https://doi.org/10.1016/j.carbpol.2016.11.036.

Poletto M., Ornaghi H.L., Zattera A.J. Materials, 2014, vol. 7(9), pp. 6105–6119. https://doi.org/10.3390/ma7096105.

Prosvirnikov D.B., Akhmetshin I.R., Gaynullina D.Sh., Prosvirnikova T.D. Vestnik Kazanskogo tekhnologicheskogo universiteta, 2014, vol. 17 (17), pp. 109–112. (in Russ.).

Published
2025-12-19
How to Cite
1. Chudina A. I., Sudakova I. G., Vorobyov S. A., Kuznetsov B. N. FRACTIONATION OF PINE BARK TO OBTAIN AN ANTHOCYANIDINS AND POWDERED CELLULOSE // Chemistry of plant raw material, 2025. № 4. P. 151-161. URL: https://journal.asu.ru/cw/article/view/18038.
Issue
No 4 (2025)
Section
Biopolymers of plants

Copyright (c) 2025 Chemistry of plant raw material

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