CHEMICAL COMPOSITION OF FRUIT AND OIL SILYBUM MARIANUM, GROWING IN THE TERRITORY OF THE REPUBLIC OF DAGESTAN

  • Arsen Shamsudinovich Ramazanov Dagestan State University Email: a_ramazanov_@mail.ru
  • Shamsiyat Abdulmedjidovna Balaeva Dagestan State University Email: balashamsiyat@mail.ru
  • Kurban Shakhbanovich Shakhbanov Dagestan State University Email: kurban199106@mail.ru
Keywords: milk thistle, Silybum marianum (L.) Gaertn., fruits, milk thistle oil, flavolignans, quality characteristics, fatty acids, mineral elements

Abstract

The object of the study were the fruits of milk thistle spotted (Silybum marianum L.) and fatty oil obtained from them by supercritical fluid extraction of carbon dioxide.

The aim of the study was to determine the chemical composition of fruits and fatty oil of milk thistle, growing in the Republic of Dagestan; to determine the quality and content of fatty acids in milk Thistle oil by gas-liquid chromatography with mass-selective detection. It is established that the fruits of Silybum marianum: contains 26±1% fatty oil and 3.4% of flavolignans; characterized by a low content of potassium, magnesium and calcium and a high content of microelements: iron, copper, zinc, chromium, strontium, manganese. The content of cadmium and lead in fruits does not exceed the MPC for medicinal plant raw materials. The indicators of oil quality from Thistle fruits are determined: the number of saponification is 187, the essential number is 183, the acid number is 4, the iodine number is 115 and the peroxide number is 2.7.

It was found that the main components of the oil obtained by supercritical fluid extraction with carbon dioxide are: linoleic (omega-6) 64±2%; oleic (omega-9) 23±1%; palmitic 7.7±0.4%; stearic 3.0±0.2%; arachinic 1.5±0.7% and myristic acid 0.17±0.06%. In the oil from the fruit of Silybum marianum discovered: potassium 13; calcium 0.5; iron 0.2; chromium 0.2; magnesium and sodium at 0.1 mg/kg.

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Author Biographies

Arsen Shamsudinovich Ramazanov, Dagestan State University

заведующий кафедрой аналитической и фармацевтической химии

Shamsiyat Abdulmedjidovna Balaeva, Dagestan State University

старший лаборант кафедры аналитической и фармацевтической химии

Kurban Shakhbanovich Shakhbanov, Dagestan State University

Учебный мастер кафедры аналитической и фармацевтической химии

References

Zimin I.M. Bibliotechka lekarstvennyh rastenij: sobranie narodnoj i nauchnoj mediciny [Library of medicinal plants: collection of folk and scientific medicine]. Saint-Petersburg, 1992, vol. 1, 264 p. (in Russ.).

Lavrenov V.K., Lavrenova G.V. Polnaya ehnciklopediya lekarstvennyh rastenij [Complete encyclopedia of medicinal plants]. Saint-Petersburg; Moscow, 1999, vol. 1, 736 p. (in Russ.).

Aliev H.U. Sochinskij nauchno-issledovatel'skij centr Rossijskoj akademii nauk. Sochi, 2015, pp. 109–117. (in Russ.).

Mamalieva M.M., Vagabova F. A., Musaeva A. M. Bioraznoobrazie i racional'noe ispol'zovanie prirodnyh resursov. Mahachkala, 2015, pp. 20–23. (in Russ.).

Gamidova N.H., Magomedov U.M., Tazhudinova Z.Sh., Omarov F.B. Izvestiya Dagestanskogo gosudarstvennogo pedagogicheskogo universiteta. Estestvennye i tochnye nauki, 2015, no. 4, pp. 47–52. (in Russ.).

Kurkin V.A., Zapesochnaya G.G., Avdeeva E.V., Ryzhov V.M., Popova A.A., Gryadunov P.E. Rastoropsha pyatnistaya [Silybum marianum]. Samara, 2010, 108 p. (in Russ.).

Sulejmanova G.V, Donkova N.V. Vestnik KrasGAU, 2016, no. 12, pp. 33–38. (in Russ.).

Kozlova V.V., Kuznecova A.A. Sovremennaya farmaciya: problemy i perspektivy razvitiya, Vladikavkaz, 2015, pp. 407–409. (in Russ.).

Kurkin V.A., Sazonova O.V, Rosihin D.V., Ryazanova T.K. Khimiia rastitel'nogo syr'ia, 2017, no. 3, pp. 101–105. DOI: 10.14258/jcprm.2017031727. (in Russ.).

Ismaili S.A., Harhar H., Gharby S. et al. Journal of Materials and Environmental Science, 2016, vol. 7, no. 6, pp. 2208–2213.

Mnacakanyan V.A., Ananikyan G.S., Babahanyan M.A., Oganesyan L.EH., Ovsepyan G.YU., Sargisyan S.A. Mezhdunarodnyj zhurnal prikladnyh i fundamental'nyh issledovanij, 2015, no 12, pp. 1445–1447. (in Russ.).

Patent 2129873 (RU). 10.05.1999. (in Russ.).

Corchete P. Bioactive molecules and medicinal plants, Springer Berlin Heidelberg, 2008, pp. 123–148.

Goncharova T. A. Ehnciklopediya lekarstvennyh rastenij: (lechenie travami) [Encyclopedia of medicinal plants: (herbal treatment)]: Vol. 1, Moscow, 1997, 560 p. (in Russ.).

Pitkevich Eh.S., Lyzikov A.N., Caprilova S.V. Problemy zdorov'ya i ehkologii, 2008, pp. 119–126. (in Russ.).

Gosudarstvennaya farmakopeya Rossijskoj Federacii. XIII izd. [State Pharmacopoeia of the Russian Federation. XIII edition], 2015, 1004 p. (in Russ.).

GOST 31665-2012. Masla rastitel'nye i zhiry zhivotnye. Poluchenie metilovykh efirov zhirnykh kislot. [State standard 31665-2012. Vegetable oils and animal fats. Production of fatty acid methyl esters]. (in Russ.).

GOST R 51483-99. Masla rastitel`ny`e i zhivotny`e zhiry`. Opredelenie metodom gazovoj khromatografii massovoj doli metilovykh e`firov individual`nykh zhirnykh kislot k ikh summe. [State standard R 51483-99. Vegetable oils and an-imal fats. Determination by the gas chromatography method of the mass fraction of methyl esters of individual fatty ac-ids to their sum]. (in Russ).

Bahl J. R., Bansal R. P., Richa Goel and Sushil Kumar. Indian Journal of Natural Products and Resources, 2015, vol. 6, issue 2, pp. 127–133.

Gasymova Sh.A., Novruzov Eh.N., Mekhtieva N.P. Khimiia rastitel'nogo syr'ia, 2017, no. 3, pp. 107–111. DOI: 10.14258/jcprm.2017031585. (in Russ.).

Assessment report on Silybum marianum (L.) Gaertn. fructus. EMA/HMPC/294188/2013, 2018. 78 p.

Ramazanov A.Sh., Shahbanov K.Sh. Khimiia rastitel'nogo syr'ia, 2018, no. 1, pp. 75–81. DOI: 10.14258/jcprm.2018012402. (in Russ.).

РАСТОРОПША ПЯТНИСТАЯ
Published
2019-01-23
How to Cite
1. Ramazanov A. S., Balaeva S. A., Shakhbanov K. S. CHEMICAL COMPOSITION OF FRUIT AND OIL SILYBUM MARIANUM, GROWING IN THE TERRITORY OF THE REPUBLIC OF DAGESTAN // Chemistry of plant raw material, 2019. № 2. P. 113-118. URL: https://journal.asu.ru/cw/article/view/4441.
Section
Low-molecular weight compounds