MODIFICATION OF WOOD WITH FATTY ACIDS OBTAINED FROM SOAP STOCK
UDC 661.728.855
Abstract
The paper considers the study of obtaining fatty acids from soap stocks. The proposed method of chemical processing of soap stock was applied for the first time and is not found in the previously published literature on the problems of chemical processing of vegetable oil waste. The composition of the isolated fatty acids of soap stock was studied by mass spectroscopy and the main chemical characteristics of the obtained fatty acids were determined. The isolated fatty acids are valuable not only as a feed additive for livestock, but also as a raw material for the chemical industry, in particular for the production of cellulose esters. The resulting fatty acids were used in the acylation of wood to obtain cellulose esters. The paper considers the kinetic regularities of the reaction of wood acylation with fatty acids of soap stock and studies the optimal conditions for the synthesis of cellulose esters from wood depending on the temperature and time of synthesis. The resulting products were investigated by IR spectroscopy, which proved the formation of an ester bond in the products obtained. When studying the kinetic regularities of the acylation of wood with fatty acids, the energy parameters were calculated in accordance with the kinetics of heterogeneous processes, which include the acylation of wood.
Downloads
Metrics
References
Friedman M., Wolf R. Clinics in Dermatology, 1996, vol. 14, no. 1, pp. 7–13. DOI: 10.1016/0738-081X(95)00102-L.
Shnyp I.A., Slepneva L.M., Krayetskaya O.F. Vestnik BNTU, 2011, no. 2, pp. 68–71. (in Russ.).
Poddenezhnyy Ye.N., Boyko A.A., Alekseyenko A.A., Drobyshevskaya N.Ye., Uretskaya O.V. Vestnik GGTU im. P.O. Sukhogo, 2015, no. 2 (61), pp. 31–41. (in Russ.).
Poyarkova T.N., Prokof’ev Yu.I., Kudrina G.V., Tarasova A.V., Sotnikova E.V. JAOCS, 2012, vol. 85, pp. 1399–1403.
Has N.J., Sckott L.M. J. Am. Oil Chem., 1996, vol. 73, pp. 1393–1401.
Watson K.S., Meierhoff C.H. American Oil Chemists’ Society, 1983, vol. 2, pp. 310–313.
Asilbekova D.T., Gusakova S.D., Nazarova I.P., Mukhamedova Kh.S, Tyshchenko A.A., Glushenkova A.I. Chemis-try of Natural Compounds, 1988, vol. 24, pp. 424–429.
Mag T.K., Green D.H., Kwong A.T. Journal of the American Oil Chemists’ Society, 1983, vol. 5, pp. 1008–1011.
Parck Y., Kim D.-K., Wang Z.-M., Lee J.-P., Parck S.-C., Lee J.-S. Korean Journal of Chemical Engineering, 2008, vol. 24, pp. 1351–1355.
Mustafa I., Tart Jon L., Van Gerpen. JAOCS, 2001, vol. 78, pp. 115–118.
Schlik L.L., Hana A.A., Schistock J.L. ASAE, 1987, vol. 33, pp. 1346–1348.
Protopopov A.V., Shumilova Ye.Yu., Neshchadimova Ye.A., Lazukina K.G. Pridneprovskiy nauchnyy vestnik «Nauka i obrazovaniye», 2019, vol. 2, no. 1, pp. 46–50. (in Russ.).
Protopopov A.V., Shumilova Ye.Yu., Neshchadimova Ye.A., Lazukina K.G. Khimiya i tekhnologiya rastitel'nykh veshchestv: Tezisy dokladov XI Vseros-siyskoy nauchnoy konferentsii s mezhdunarodnym uchastiyem i shkoloy molodykh uchenykh. [Chemistry and technology of plant substances: Abstracts of the XI All-Russian scientific confer-ence with international participation and a school of young scientists]. Syktyvkar, 2019, p. 185. (in Russ.).
Protopopov A.V., Voroshilova A.V., Bobrovskaya S.A. Mezhdunarodnyy nauchno-issledovatel'skiy zhurnal, 2017, no. 12 (66), pp. 152–155. (in Russ.).
Bobrovskaya S.A., Shleina A.N., Kuris Yu.Ye., Shumilova Ye.Yu., Protopopov A.V. Problemy nauchnoy mysli, 2018, vol. 3, no. 5, pp. 59–62. (in Russ.).
Protopopov A.V. Golod A.V., Bovina A.Ye., Vagina D.S. Problemy nauchnoy mysli, 2018, vol. 3, no. 5, pp. 63–66. (in Russ.).
Protopopov A.V., Bobrovskaya S.A., Shumilova Ye.Yu. Materialy XIV Mezhdunarodnoy nauchno-prakticheskoy konferentsii «Obrazovaniye i nauka bez granits – 2018». [Materials of the XIV International Scientific-Practical Con-ference, "Education and Science Without Borders - 2018"]. Przemyśl, 2018, vol. 3, pp. 25–29 (in Russ.).
Protopopov A.V., Kuris Yu.Ye., Golod A.V., Bovina A.Ye. Biotekhnologiya i obshchestvo v XXI veke. [Biotechnology and society in the XXI century]. Barnaul, 2018, pp. 241–247. (in Russ.).
Kuris Yu.Ye., Shleina A.N., Vagina D.S., Protopopov A.V. Biotekhnologiya i obshchestvo v XXI veke. [Biotechnology and society in the XXI century]. Barnaul, 2018, pp. 247–254. (in Russ.).
Protopopov A.V., Bobrovskaya S.A., Shumilova Ye.Yu. Biotekhnologiya i obshchestvo v XXI veke. [Biotechnology and society in the XXI century]. Barnaul, 2018, pp. 161–169. (in Russ.).
Copyright (c) 2022 chemistry of plant raw material

This work is licensed under a Creative Commons Attribution 4.0 International License.

This work is licensed under a Creative Commons Attribution 4.0 International License.
The authors, which are published in this journal, agree to the following conditions:
1. Authors retain the copyright to the work and transfer to the journal the right of the first publication along with the work, at the same time licensing it under the terms of the Creative Commons Attribution License, which allows others to distribute this work with the obligatory indication of the authorship of this work and a link to the original publication in this journal .
2. The authors retain the right to enter into separate, additional contractual agreements for the non-exclusive distribution of the version of the work published by this journal (for example, to place it in the university depository or to publish it in a book), with reference to the original publication in this journal.
3. Authors are allowed to post their work on the Internet (for example, in a university repository or on their personal website) before and during the review process of this journal, as this may lead to a productive discussion, as well as more links to this published work.







