ADSORPTION ACTIVITY OF POLYPHEPAN-KAOLIN MECHANOCOMPOSITES IN RELATION TO INORGANIC IONS
UDC 543.544-414.5(552.525)
Abstract
The purpose of the work was to study the influence of mechanochemical activation on the physical characteristics and adsorption activity of mechanically activated composites based on polyphepane and kaolin in relation to inorganic ions. To achieve the goal, the following tasks were completed: samples of mechanically activated composite sorbents were prepared, the adsorption activity of polyphepane, kaolin and composites was experimentally determined, the values of ion extractability and the relative deviation of the experimental adsorption activity from the additive value of the mixture of starting substances without mechanical activation were calculated. The adsorption value was determined using the X-ray fluorescence method. It was revealed that the main contribution to adsorption was made by the true density index of the composites. The most actively sorbed cations from solutions by composites were Fe3+ (200.9 mg/g), Zn2+ (140.9 mg/g) and Cu2+ (109.5 mg/g); for anions in absolute terms, the maximum was observed for I- (99.3 mg/g). The relative deviation of the experimental adsorption activity in relation to mixtures without mechanical activation was maximum for [AuCl4]-, Cu2+ and AsO33- (ε 486.1%, 458% and 358.8%, respectively). It was revealed that the degree of recovery for cations was greater for polyphepane, and for anions - for kaolin. The most effective composite sorbents were removed from solutions of [AuCl4]-, Cu2+ and I- (α>300%), while the degree of recovery for SeO32- and AsO33- had minimal values (α no more than 50%). The data obtained can be used for the production of sorbents that are safe for the biosphere, used to purify wastewater from toxic elements, as well as for their concentration and extraction during the processing of mineral resources. Prospects for the development of research include studying the kinetics of sorption processes on prepared composites and other methods of their activation.
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