RECENT ADVANCES IN MECHANOCHEMICAL PROCESSING OF PLANT RAW MATERIALS
Abstract
Overview of current data published on the subject of mechanically activated processes of processing plant raw materials is carried out in the work. Examples of physical and chemical processes occurring during mechanical treatment of individual substances and plant raw materials are listed. Mechanochemical treatment allows to increase the reactivity of the substances included in the plant raw material by increasing the specific surface area (such as the area «suitable» to interact with the reagents, enzymes), reducing cellulose crystallinity and the overall disordering supramolecular structure of the cell walls. Mechanochemical treatment of plant raw materials together with enzymes can produce of high reactive composites in which reagents are equally distributed over the substrate by no diffusive way (by mechanically way). Subsequent chemical reactions with participation of these composites proceed more efficiently due reducing the diffusion paths and improve the stability of target substances or enzymes (for biotechnological processes), and extraction of reaction products occurs more completely. The economic efficiency is often a limiting factor in implementation of new technologies, including one or more stages of crushing or mechanical activation, determined by the cost of mechanical treatment.Downloads
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Kuznetsov B.N., Chesnokov N.V., Yatsenkova O.V., Sharypov V.I. Russian Chemical Bulletin, 2013, vol. 62, no. 7, pp. 1493–1502.
Kushnir E.Y., Autlov S.A., Bazarnova N.G. Russian Journal of Bioorganic Chemistry, 2015, vol. 41, no. 7, pp. 713–718.
Mikhailenko M.A., Shakhtshneider T.P., Drebushchak V.A., SkvortsovaG.P., Boldyrev V.V. Chemistry of Natural Compounds, 2011, vol. 47, no. 2, pp. 229–233.
Seliutina O.Iu., Poliakov N.E., Meteleva E.S., Dushkin A.V. Khimiia v interesakh ustoichivogo razvitiia, 2015, vol. 23, no. 5, pp. 549–560. (in Russ.).
Manaenkov O.V., Filatova A.E., Makeeva O.Y., Kislitsa O.V., Doluda V.Yu., Sidorov A.I., Matveeva V.G., Sul’man E.M. Catalysis in Industry. 2014. Vol. 6. N2. Pp. 150–157.
Bazarnova N.G., Markin V.I., Katrakov I.B., Kolosov P.V., Cheprasova M.Y., Kalyuta E.V. Russian Journal of Gen-eral Chemistry, 2015, vol. 82, no. 5, pp. 947–954.
Shapolova E.G., Lomovsky O.I. Russian Journal of Bioorganic Chemistry, 2013, vol. 39, no. 7, pp. 765–770.
Galbe M., Zacchi G. Applied Microbiology and Biotechnology, 2002, vol. 59, pp. 618–628.
Lynd L.R., Weimer P.J., Zyl W.H., Pretorius I.S. Microbiology and Molecular Biology Reviews, 2002, vol. 66, no. 3, pp. 506–577.
Zheng Y., Pan Z., Zhang R. International Journal of Agricultural and Biological Engineering, 2009, vol. 2, no. 3, pp. 51–68.
Taherzadeh M.J., Karimi K. International Journal of Molecular Sciences, 2008, vol. 9, pp. 1621–1651.
Bai F.W., Anderson W.A., Moo-Young M. Biotechnology Advances, 2008, vol. 26, no. 1, pp. 89–105.
Skiba E.A., Budaeva V.D., Makarova E.I., Pavlov I.N., Zolotukhin V.N., Sakovich G.V. Vestnik Kazanskogo tekhnologicheskogo universiteta, 2013, vol. 16, no. 22, pp. 202–205. (in Russ.).
Makarova E.I., Budaeva V.V., Skiba E.A., Sakovich G.V. Catalysis in Industry, 2014, vol. 6, no. 1, pp. 67–71.
Sørensen A., Teller P.J., Hilstrøm T., Ahring B.K. Bioresource Technology, 2008, vol. 99, no. 14, pp. 6602–6607.
Ge X., Burner D.M., Xu J., Phillips G.C., Sivakumar G. Biotechnology Journal, 2011, vol. 6, no. 1, pp. 66–73.
Gaveau D.L.A., Balzter H., Plummer S. Forest Ecology and Management, 2003, vol. 174, no. 1–3, pp. 65–75.
Goliazimova O.V. Mekhanicheskaia aktivatsiia fermentativnogo gidroliza tselliulozy i lignotselliuloznykh mate-rialov: dis. … kand. khim. nauk. [Mechanical activation of enzymatic hydrolysis of cellulose and lignocellulosic materials: dis. ... cand. Chem. Sciences]. Novosibirsk, 2010, 164 p. (in Russ.).
Sinitsyn A.P., Gusakov A.V., Chernoglazov V.M. Biokonversiia lignotselliuloznykh materialov. [Bioconversion of lignocellulosic materials]. Moscow, 1995, 224 p. (in Russ.).
Kumar P., Barrett D.M., Delwiche M.J., Stroeve P. Industrial and Engineering Chemistry Research, 2009, vol. 48, no. 8, pp. 3713–3729.
Fang Z. Pretreatment techniques for biofuels and biorefineries. Berlin, 2013, 457 p.
Kumakura M., Kojima T., Kaetsu I. Biomass., 1982, vol. 2, no. 4, pp. 299–308.
Chaturvedi V., Verma P. 3 Biotech., 2013, vol. 3, no. 5, pp. 415–431.
Bychkov A.L., Lomovskii O.I. Russian Journal of Applied Chemistry, 2010, vol. 83, no. 6, pp. 1106–1108.
Lomovsky O.I., Lomovsky I.O. Enhancing Extraction Processes in the Food Industry, London, New York, 2011, pp. 61–398.
Boldyrev V.V. Materials Science Forum, 1996, vol. 225, pp. 511–520.
Politov A., Golyazimova O. Faraday Discussions, 2014, vol. 170, pp. 345–356.
Bychkov A.L., Korolev K.G., Lomovsky O.I. Applied Biochemistry and Biotechnology, 2010, vol. 162, pp. 2008–2014.
Grigoryeva T.F., Barinova A.P., Ancharov A.I., Lyakhov N.Z. Journal of Alloys and Compounds, 2007, vol. 434–435, pp. 540–541.
Grigor'eva T.F., Barinova A.P., Liakhov N.Z. Mekhanokhimicheskii sintez v metallicheskikh sistemakh. [Mechanochemical synthesis in metallic systems]. Novosibirsk, 2008, 312 p. (in Russ.).
Avvakumov E.G. Mekhanicheskie metody aktivatsii khimicheskikh protsessov. [Mechanical methods of activation of chemical processes]. Novosibirsk, 1986, 303 p. (in Russ.).
Boldyrev V.V. Powder Technology, 2002, vol. 122, pp. 247–254.
Radtsig V.A. Khimicheskaia fizika, 2004, vol. 23, no. 10, pp. 70–109. (in Russ.).
Simionescu C.I., Oprea C.V. Mecanochimia compusilor macromoleculari, Bucharest, 1967, 344 p.
Butyagin P.Yu. Colloid journal of the Russian Academy of Sciences, 1997, vol. 59, no. 4, pp. 460–467.
Avvakumov E., Senna M., Kosova M. Soft mechanochemical synthesis: a basis for new chemical technologies, Boston, 2001, 207 p.
Tanaka K. Solvent-free organic synthesis, Weinheim, 2006, 442 p.
Toda F. Organic solid-state reactions, Dordrecht, 2013, 275 p.
Toda F. Accounts of Chemical Research, 1995, vol. 28, no. 12, pp. 480–486.
Xie J., Lin Y.-S., Shi X.-J., Zhu X.-Y., Su W.-K., Wang P. Industrial Crops and Products, 2013, vol. 43, pp. 276–282.
Meullemiestre A., Breil C., Abert-Vian M., Chemat F. Bioresource Technology, 2016, vol. 211, pp. 190–199.
Xu W., Yu J., Feng W., Su W. Molecules, 2016, vol. 21, no. 5, article number 540, doi:10.3390/molecules21050540
Korolev, K.G.; Lomovskii, O.I.; Rozhanskaya, O.A.; Vasi’ev, V.G. Chemistry of Natural Compounds, 2003, vol. 39, pp. 366–372.
Pankrushina N., Nikitina I., Chernjak E., Myz C., Shakhtshneider T., Boldyrev V. Materials and Manufacturing Pro-cesses, 2008, vol. 23, no. 6, pp. 561–565.
Gama F.M., Mota M. Biocatalysis and Biotransformation, 1997, vol. 15, no. 3, pp. 221–236.
Yeh A.-I., Huang Y.-C., Hsin S. Carbohydrate Polymers, 2010, vol. 79, no. 1, pp. 192–199.
Rahikainen J., Mikander S., Marjamaa K., Tamminen T., Lappas A., Viikari L., Kruus K. Biotechnology and Bioen-gineering, 2011, vol. 108, no. 12, pp. 2823–2834.
Singh R., Shukla A., Tiwari S., Srivastava M. Renewable and Sustainable Energy Reviews, 2014, vol. 32, pp. 713–728.
Kumar R., Hu F., Hubbell C.A., Ragauskas A.J., Wyman C.E. Bioresource Technology, 2013, vol. 130, pp. 372–381.
Cantarella M., Mucciante C., Cantarella L. Bioresource Technology, 2014, vol. 156, pp. 48–56.
Umikalsom M.S., Ariff A.B., Karim M.I.A. Journal of Agricultural and Food Chemistry, 1998, vol. 46, no. 8, pp. 3359–3364.
Hames B.R., Thomas S.R., Sluiter A.D. Applied Biochemistry and Biotechnology, 2003, vol. 105-108, pp. 5–16.
Bychkov A.L., Ryabchikova E.I., Korolev K.G., Lomovsky O.I. Biomass and Bioenergy, 2012, vol. 47, pp. 260–267.
Goliazimova O.V., Politov A.A., Lomovskii O.I. Khimiia rastitel'nogo syr'ia, 2009, no. 2, pp. 53–57. (in Russ.).
Goliazimova O.V., Politov A.A., Lomovskii O.I. Khimiia rastitel'nogo syr'ia, 2009, no. 2, pp. 59–63. (in Russ.).
Hall M., Bansal P., Lee J.H., Realff M.J., Bommarius A.S. FEBS Journal, 2010, vol. 277, no. 6, pp. 1571–1582.
Sinitsyn A.P., Kovalev G.V., Messa-Manresa S.R. Khimiia drevesiny, 1984, no. 5, pp. 60–71. (in Russ.).
Yoshida M., Liu Y., Uchida S., Kawarada K., Ukagami Y., Ichinose H., Kaneko S., Fukuda K. Bioscience, Biotech-nology and Biochemistry, 2008, vol. 72, no. 3, pp. 805–810.
Hermans P.H., Weidinger A. Journal of American Chemical Society, 1946, vol. 68, pp. 2547–2552.
Yakunin N.A., Zavadskii A.E., Yakunina E.N., Moryganov A.P. Polymer Science. Series A, 2010, vol. 52, no. 2, pp. 134–138.
Iyer P.B., Sreenivasan S., Chidambareswaran P.K., Patil N.B. Textile Research Journal, 1984, vol. 54, no. 11, pp. 732–735.
Nakamura K., Hatakeyama T., Hatakeyama H. Textile Research Journal, 1981, vol. 72, no. 9, pp. 607–613.
Ouajai S., Shanks R.A. Cellulose, 2006, vol. 13, pp. 31–44.
Paes S.S., Sun S., MacNaughtan W., Ibbett R., Ganster J., Foster T.J., Mitchell J.R. Cellulose, 2010, vol. 17, pp. 693–709.
Bertran M.S., Dale B.E. Biotechnology and Bioengineering, 1985, vol. 27, pp. 177–181.
Wormald P., Wickholm K., Larsson P.T., Iversen T. Cellulose, 1996, vol. 3, pp. 141–152.
Liang X.H., Gu L.Z., Ding E.Y. Wood Science and Technology, 1993, vol. 27, no. 6, pp. 461–467.
Orlov D.V., Bychkov A.L., Lomovsky I.O. VIII International Conference of Mechanochemistry and Mechanical Al-loying, Crakow, 2014, p. 43.
Orlov D.V., Lomovskii I.O., Lomovskii O.I. II Vserossiiskaia konferentsiia «Goriachie tochki khimii tverdogo tela: mekhanizmy tverdofaznykh protsessov». [II All-Russian Conference "Hot Spots of Solid State Chemistry: Mechanisms of Solid-Phase Processes"]. Novosibirsk, 2015, p. 36. (in Russ.).
Zhou C., Liu G., Wang X., Qi C. Bioresource Technology, 2016, vol. 218, pp. 418–427.
Patent 4706903 (USA). 17.11.1987.
Patent 5366558 (USA). 22.11.1994.
Akhtar M. Holzforschung, 1994, vol. 48, pp. 199–202.
Zhao H., Kwak J.H., Wang Y., Franz J.A., White J.M., Holladay J.E. Energy & Fuels, 2006, vol. 20, pp. 807–811.
Burdukov A.P., Popov V.A., Chernetskii M.Iu., Dekterev A.A., Lomovskii O.I., Bychkov A.L. Polzunovskii vestnik, 2013, no. 4/3, pp. 16–27. (in Russ.).
Piriou B., Vaitilingom G., Veyssiere B., Cuq B., Rouau X. Progress in Energy and Combustion Science, 2013, vol. 39, pp. 169–188.
Siyi L., Bo X., Zhiquan H., Shiming L., Maoyun H. Energy Conversion and Management, 2010, vol. 51, pp. 2098–2102.
Burdukov A.P., Popov V.I., Iusupov T.S., Lomovskii O.I. Khimiia v interesakh ustoichivogo razvitiia, 2009, vol. 17, no. 5, pp. 471–478. (in Russ.).
Burdukov A.P., Popov V.I., Faleev V.A., Iusupov T.S. Polzunovskii vestnik, 2010, no. 1, pp. 93–98. (in Russ.).
Iusupov T.S., Shumskaia L.G., Burdukov A.P. Fiziko-tekhnicheskie problemy razrabotki poleznykh iskopaemykh, 2009, no. 4, pp. 111–116. (in Russ.).
Iusupov T.S., Burdukov A.P. VIII Vserossiiskaia konferentsiia s mezhdunarodnym uchastiem «Gorenie tverdogo topliva». [VIII All-Russian Conference with International Participation "Combustion of Solid Fuel"]. Novosibirsk, 2012, pp. 112.1–112.3. (in Russ.).
Luo S., Liu C., Xiao B., Xiao L. Renewable Energy, 2011, vol. 36, pp. 578–582.
Repellin V., Govin A., Rolland M., Guyonnet R. Biomass and Bioenergy, 2010, vol. 34, pp. 923–930.
Phanphanich M., Mani S. Bioresource Technology, 2011, vol. 102, pp. 1246–1253.
Grethlein H.E., Converse A.O. Bioresource Technology, 1991, vol. 36, no. 2, pp. 77–82.
Kenealy W., Klungness J., Tshabalala M. 2003 TAPPI Fall Technical Conference: Engineering, Pulping & PCE&I. Atlanta, 2003, p. 9
Klesov A.A., Sinitsyn A.P. Bioorganicheskaia khimiia, 1981, vol. 7, no. 12, pp. 1801–1812. (in Russ.).
Namazi A.B., Jia C.Q., Allen D.G. Water Science & Technology, 2010, vol. 62, no. 11, pp. 2637–2646.
Horstmann B.J., Kennedy C.N., Chase H.A. Journal of Chromatography, 1986, vol. 361, pp. 179–190.
Wiman M., Dienes D., Hansen M.A.T., Van Der Meulen T., Zacchi G., Lidén G. Bioresource Technology, 2012, vol. 126, pp. 208–215.
Patent 7709042 (USA). 4.05.2010.
Patent 5114488 (USA). 19.05.1992.
Patent 101085994 (China). 12.12.2007.
Patent 2514408 (RU). 27.04.2014. (in Russ.).
Akhtar M., Lentz M.J., Horn E.G. Resources. Conservation and Recycling, 2010, vol. 28, pp. 241–252.
Masarin F., Pavan P.C., Vicentim M.P., Souza-Cruz P.B., Loguercio-Leite C., Ferraz A. Holzforschung, 2009, vol. 63, pp. 259–263.
Lin Z., Huang H., Zhang H., Zhang L., Yan L., Chen J. Applied Biochemistry and Biotechnology, 2010, vol. 162, pp. 1872–1880.
Hilgert J., Meine N., Rinaldi R., Schüth F. Energy & Environmental Science, 2013, vol. 6, pp. 92–96.
Millett M.A., Effland M.J., Caulfield D.F. Hydrolysis of cellulose: mechanisms of enzymatic and acid catalysis. American Chemical Society Advances in Chemistry, Series 181, Washington, 1979, pp. 71–89.
Silva G.G., Couturier M., Berrin J.-G., Buleon A., Rouau X. Bioresource Technology, 2012, vol. 103, pp. 192–200.
Alekseeva O.V., Rozhkova O.V., Prusov A.N. Fibre Chemistry, 1997, vol. 29, no. 2, pp. 103–105.
Prusov A.N., Zheleznov K.N., Alekseeva O.V., Padokhin V.A., Rozhkova O.V. Colloidal Journal, 2002, vol. 64, no. 5, pp. 601–604.
Kokko L., Tolvanen H., Hamalainen K., Raiko R. Biomass and Bioenergy, 2012, vol. 42, pp. 219–223.

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